Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Crystal structure of pyridinium nonabromodiantimonate(III) dibromide

S. K. Porter  and  R. A. Jacobson  

Abstract

Pyridinium nonabromodiantimonate(III), (C5H5NH)5(SbIII2Br9)(Br)2, has been prepared and its crystal structure has been determined and refined by Patterson, Fourier, and full-matrix least-squares techniques to a final R of 0·109. The crystals were monoclinic, space group B2m with a= 18·01, b= 30·14, c= 7·82 A°, β= 95·02° and Z=4.

Each [Sb2Br9]3– anion has the form of two distorted SbBr6 octachedra sharing a face : the average Sb–Br distances to the bridging and terminal bromines are 3·00 and 2·63 Å, respectively. There are two bromide ions per formula unit that appear to be for packing purposes only.

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Article information

DOI
https://doi.org/10.1039/J19700001359
Article type
Paper

J. Chem. Soc. A, 1970, 1359-1362

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Crystal structure of pyridinium nonabromodiantimonate(III) dibromide

S. K. Porter and R. A. Jacobson, J. Chem. Soc. A, 1970, 1359 DOI: 10.1039/J19700001359

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