Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Tungsten(V) oxytrichloride and oxytribromide. Part II. Reactions with donor molecules and the related behaviour of molybdenum(V) oxytribromide

P. C. Crouch,   G. W. A. Fowles,   P. R. Marshall  and  R. A. Walton  

Abstract

The oxytrihalides MoOBr3, WOCl3, and WOBr3 react with a variety of oxygen and nitrogen donor molecules to form compounds of empirical formula MOX3,2L which are formulated as monomers containing terminal Mo[double bond, length half m-dash]O or W[double bond, length half m-dash]O groups. The compounds have been characterised by oxidation-state titrations, infrared and electronic spectral measurements, and temperature range (320–80°k;) magnetic studies. The direct reaction of WOCl3 with pyridine or trimethylamine give the dark blue 1 : 1 adducts WOCl3,py or WOCl3,NMe3, respectively, whose magnetic properties are very similar to those of WOCl3 itself, and which are believed to be octahedral polymers with W–O–W bridges.

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Article information

DOI
https://doi.org/10.1039/J19680001634
Article type
Paper

J. Chem. Soc. A, 1968, 1634-1638

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Tungsten(V) oxytrichloride and oxytribromide. Part II. Reactions with donor molecules and the related behaviour of molybdenum(V) oxytribromide

P. C. Crouch, G. W. A. Fowles, P. R. Marshall and R. A. Walton, J. Chem. Soc. A, 1968, 1634 DOI: 10.1039/J19680001634

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