Issue 0, 1968

The reactivity of co-ordinated oxalate. Part VI. Acid-catalysed aquation of the trisoxalatocobaltate(III) anion

Abstract

The stoicheiometry of the acid-catalysed aquation of the trisoxalatocobaltate(III) anion is represented by 10H++ 2Co(C2O4)33– 2Co2++ 5H2C2O4+ 2CO2. The rate of aquation is repressed by addition of oxalate ions and therefore a reversible dissociation yielding oxalate ions precedes the electron-transfer step.

Article information

Article type
Paper

J. Chem. Soc. A, 1968, 1415-1417

The reactivity of co-ordinated oxalate. Part VI. Acid-catalysed aquation of the trisoxalatocobaltate(III) anion

J. Aggett and A. L. Odell, J. Chem. Soc. A, 1968, 1415 DOI: 10.1039/J19680001415

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