By photolysing azomethane in the presence of the silane the following Arrhenius parameters have been obtained for hydrogen-abstraction reactions of methyl radicals: [graphic omitted] The high reactivities of chlorosilanes in free-radical reactions appear to be due to abnormally high A-factors rather than to low activation energies.
J. A. Kerr, D. H. Slater and J. C. Young, J. Chem. Soc. A, 1966, 104 DOI: 10.1039/J19660000104
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