Issue 11, 1995

Synthesis of [Mo(η6-NC5H3Me2-2,6)(η6-C6H5Me)]: photoelectron spectra and electronic structure of some transition-metal η6-2,6-dimethylpyridine complexes

Abstract

Synthesis of the mixed-ring sandwich compound [Mo(η6-NC5H3Me2-2,6)(η6-C6H5Me)] is reported. Photoelectron spectroscopic studies of [M(η6-NC5H3Me2-2,6)2], where M = Ti, V, Cr or Mo and [Mo(η6-NC5H3Me2-2,6)(η6-C6H5Me)] established that these sandwich compounds are electronically very similar to the bis(arene) analogues, and that 2,6-dimethylpyridine is a better δ acceptor than benzene.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 1873-1877

Synthesis of [Mo(η6-NC5H3Me2-2,6)(η6-C6H5Me)]: photoelectron spectra and electronic structure of some transition-metal η6-2,6-dimethylpyridine complexes

J. Ashmore, J. C. Green, M. L. H. Green, M. L. Smith, C. Mehnert and E. J. Wucherer, J. Chem. Soc., Dalton Trans., 1995, 1873 DOI: 10.1039/DT9950001873

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