Issue 13, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Template synthesis, structure and properties of a bis(macrocyclic) dinickel(II) complex based on a 14-membered hexaaza unit

Vladimir B. Arion,   Nicolai V. Gerbeleu,   Veaceslav G. Levitsky,   Yuri A. Simonov,   Alexandr A. Dvorkin  and  Polina N. Bourosh  

Abstract

Template condensation of [Ni2L2]{H6L2= tetrakis[1-(3-methylisothiosemicarbazono)ethyl]ethane} with 3-ethoxyacrylaldehyde in dimethylformamide resulted in a new type of dinickel(II) bis(macrocyclic) complex, in which two hexaazamacrocyclic subunits are linked by a single C–C bond. The complex was characterized by means of spectral analysis (UV/VIS, 1H NMR, electron-impact mass), magnetic susceptibility measurements and X-ray analysis. Peculiarities of the crystal structure in comparison to related mono- and bi-nuclear species were revealed.

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Article information

DOI
https://doi.org/10.1039/DT9940001913
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1913-1916

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Template synthesis, structure and properties of a bis(macrocyclic) dinickel(II) complex based on a 14-membered hexaaza unit

V. B. Arion, N. V. Gerbeleu, V. G. Levitsky, Y. A. Simonov, A. A. Dvorkin and P. N. Bourosh, J. Chem. Soc., Dalton Trans., 1994, 1913 DOI: 10.1039/DT9940001913

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