Issue 8, 1987
From the journal:

Journal of the Chemical Society, Dalton Transactions

Lamellar inorganic ion exchangers. Proton–copper(II) ion exchange in γ-titanium bis(hydrogenphosphate)

Celia Alvarez,   Ricardo Llavona,   José R. García,   Marta Suárez  and  Julio Rodríguez  

Abstract

The behaviour of γ-Ti(HPO4)2·2H2O in the exchange of Cu2+ has been studied. Exchange isotherms and pH curves were obtained at 25.0,40.0, and 55.0 (±0.1)°C. Half-exchanged phases TiHCu0.5(PO4)2·2.5H2O (interlayer distance 12.4 Å), TiHCu0.5(PO4)2·H2O (10.7 Å), and TiHCu0.5(PO4)2(9.4 Å) were detected. The crystalline solid phases were examined by X-ray diffraction. The free energy, enthalpy, and entropy of the exchange reaction are reported.

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Article information

DOI
https://doi.org/10.1039/DT9870002045
Article type
Paper

J. Chem. Soc., Dalton Trans., 1987, 2045-2050

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Lamellar inorganic ion exchangers. Proton–copper(II) ion exchange in γ-titanium bis(hydrogenphosphate)

C. Alvarez, R. Llavona, J. R. García, M. Suárez and J. Rodríguez, J. Chem. Soc., Dalton Trans., 1987, 2045 DOI: 10.1039/DT9870002045

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