Issue 1, 1987
From the journal:

Journal of the Chemical Society, Dalton Transactions

Organotin biocides. Part 8. The crystal structure of triphenyltin formate and a comparative variable-temperature tin-119 Mössbauer spectroscopic study of organotin formates and acetates

Kieran C. Molloy,   Kieran Quill  and  Ian W. Nowell  

Abstract

The structure of triphenyltin formate has been determined by an X-ray study. Crystal data: monoclinic, space group B21/a, a= 20.176(8), b= 15.539(6), c= 21.952(10)Å, β= 90.30(6)°, Z= 16. The geometry about tin is trigonal bipyramidal with a trans-O2SnR3 stereochemistry (R = Ph), leading to a chain polymeric structure for the lattice. The geometric distortions which accompany polymer formation are assessed, and used to interpret variable-temperature Mössbauer spectroscopic data for triphenyl-, tricyclohexyl-, and trimethyl-tin formates and acetates.

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Article information

DOI
https://doi.org/10.1039/DT9870000101
Article type
Paper

J. Chem. Soc., Dalton Trans., 1987, 101-106

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Organotin biocides. Part 8. The crystal structure of triphenyltin formate and a comparative variable-temperature tin-119 Mössbauer spectroscopic study of organotin formates and acetates

K. C. Molloy, K. Quill and I. W. Nowell, J. Chem. Soc., Dalton Trans., 1987, 101 DOI: 10.1039/DT9870000101

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