Issue 8, 1982
From the journal:

Journal of the Chemical Society, Dalton Transactions

Studies of phosphazenes. Part 14. The tautomerism of oxocyclotriphosphazadienes

K. S. Dhathathreyan,   S. S. Krishnamurthy,   A. R. Vasudeva Murthy,   Robert A. Shaw  and  Michael Woods  

Abstract

The tautomeric behaviour of ‘monohydroxycyclotriphosphazatrienes’ has been investigated by 31P n.m.r. spectroscopy. These derivatives exist as oxocyclotriphosphazadiene tautomers in which the hydrogen atom is attached to a ring nitrogen atom α to the phosphoryl group. Three types of prototropic behaviour are observed : (a) no exchange is detected and only one tautomer is present [e.g. N3HP3(NHBut)2R3O (R = OMe or OEt)]; (b) exchange takes place between two equivalent sites and only one tautomer is observed [e.g. N3HP3R5O (R = OMe or OPh); N3HP3Ph4RO (R = OMe or OEt)]; and (c) exchange occurs between two non-equivalent sites and two tautomers are present [e.g. N3HP3Ph2R3O (R = OMe, OEt, or OPrn)]. It is shown that basicity calculations using substituent constants have predictive value since they are in good agreement with the spectroscopic observations.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9820001549
Article type
Paper

J. Chem. Soc., Dalton Trans., 1982, 1549-1554

Permissions

Request permissions

Studies of phosphazenes. Part 14. The tautomerism of oxocyclotriphosphazadienes

K. S. Dhathathreyan, S. S. Krishnamurthy, A. R. V. Murthy, R. A. Shaw and M. Woods, J. Chem. Soc., Dalton Trans., 1982, 1549 DOI: 10.1039/DT9820001549

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements