The hydrolysis of copper(II) has been investigated by potentiometric titration at 25 °C in 0.10 mol dm–3 potassium nitrate. Advanced computing techniques have been used for data treatment. For the species [Cu(OH)]+, [Cu2(OH)2]2+, and [Cu3(OH)4]2+, values for –log βpq are found to be 7.71 (0.04),10.99 (0.02), and 21.62 (0.03), respectively, the estimated standard deviations being in parentheses.
R. N. Sylva and M. R. Davidson, J. Chem. Soc., Dalton Trans., 1979, 232 DOI: 10.1039/DT9790000232
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