Issue 20, 2023
From the journal:

RSC Advances

Aryl fluorosulfates: powerful and versatile partners in cross-coupling reactions

Shelesh Krishna Saraswat,a   Ramanjaneyulu Seemaladinne,b   Media Noori Abdullah, ORCID logo *c   Halim Zaini,d   Nabeel Ahmad, ORCID logo e   Nafis Ahmadf  and  Esmail Vessally ORCID logo g  

* Corresponding authors

a Department of ECE, Gla University, Mathura, India

b Department of Chemistry and Bio Chemistry, Lamar University, Beaumont, Texas, USA

c Department of Chemistry, College of Science, Salahaddin University-Erbil, Kurdistan Region, Iraq
E-mail: media.abdullah@su.edu.krd

d Departement Chemical Engineering of Politeknik Negeri Lhokseumawe, Indonesia

e Department of Biotechnology, School of Allied Sciences, Dev Bhoomi Uttarakhand University, Dehradun-248007, Uttarakhand, India

f Department of Physics, College of Science, King Khalid University, P.O. Box: 960, Abha 61421, Kingdom of Saudi Arabia

g Department of Chemistry, Payame Noor University, P.O. Box 19395-1697, Tehran, Iran

Abstract

Aryl fluorosulfates are versatile building blocks in organic synthesis and have gained increasing attention in SuFEx (Sulfur Fluoride Exchange) click chemistry. They are easily and conveniently prepared from phenols using sulfuryl fluoride SO2F2 as a low-cost sulfonyl fluoride provider. Recently, they served as less toxic and more atom economical alternatives to triflates in an impressive number of carbon–carbon and carbon-heteroatom cross-coupling reactions. In this review, we summarize the current advances and developments in applying aryl fluorosulfates as electrophilic partners in cross-coupling reactions.

Graphical abstract: Aryl fluorosulfates: powerful and versatile partners in cross-coupling reactions

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Article information

DOI
https://doi.org/10.1039/D3RA01791E
Article type
Review Article
Submitted
18 Mar 2023
Accepted
20 Apr 2023
First published
03 May 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 13642-13654

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Aryl fluorosulfates: powerful and versatile partners in cross-coupling reactions

S. K. Saraswat, R. Seemaladinne, M. N. Abdullah, H. Zaini, N. Ahmad, N. Ahmad and E. Vessally, RSC Adv., 2023, 13, 13642 DOI: 10.1039/D3RA01791E

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