Issue 22, 2023
From the journal:

Green Chemistry

Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction†

Renata A. Maia, ORCID logo a   Audrey Fluck, ORCID logo a   Catalin Maxim, ORCID logo b   Benoît Louis ORCID logo *c  and  Stéphane A. Baudron ORCID logo *a  

* Corresponding authors

a CNRS, CMC UMR 7140, Université de Strasbourg, 4 rue Blaise Pascal, F-67000 Strasbourg, France
E-mail: sbaudron@unistra.fr

b Faculty of Chemistry, University of Bucharest, 4-12 Regina Elisabeta Boulevard, 030018, sector 3, Bucharest, Romania

c CNRS, ICPEES UMR 7515, Université de Strasbourg, 25 rue Becquerel, F-67087 Strasbourg, France
E-mail: blouis@unistra.fr

Abstract

A green alternative approach to the chiral induction of a metal–organic framework (MOF) has been explored using the natural deep eutectic solvents (DES) proline : thymol (1 : 7) and menthol : thymol (1 : 1). These solvents have been successfully employed for the preparation of the MIL-103 MOF and lead to an enantioenrichment of the porous material when used in enantiopure form, as demonstrated by circular dichroism.

Graphical abstract: Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D3GC02993J
Article type
Communication
Submitted
10 Aug 2023
Accepted
17 Oct 2023
First published
18 Oct 2023
This article is Open Access
Creative Commons BY-NC license

Green Chem., 2023,25, 9103-9108

Permissions

Request permissions

Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction

R. A. Maia, A. Fluck, C. Maxim, B. Louis and S. A. Baudron, Green Chem., 2023, 25, 9103 DOI: 10.1039/D3GC02993J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements