Issue 7, 2023

Improvement of a multi-tubular Fischer–Tropsch reactor with gas recycle by appropriate combination of axial activity distribution and gas velocity

Abstract

Fischer–Tropsch fixed bed synthesis is frequently conducted with a gas recycle and a CO conversion per pass of less than about 60%. In this paper, we have investigated the influence of a gas recycle on the performance of a multitubular reactor (tube length 12 m, diameter 3 cm) for different total CO conversions (XCO,total) and superficial gas velocities (us). The impact of the axial distribution of the intrinsic activity of the Co catalyst in the tubes was also studied. XCO,total is 95% for the optimal value of us of 1 m s−1 combined with a constant activity coefficient Ca of 3 (which equals a Co content of the catalyst of 30 wt%); the conversion per pass is then 45%. Further improvement (XCO,per pass = 47%) is possible by using tubes with two zones of equal length (6 m) and a suitable activity distribution (Ca,1 = 2.5, Ca,1 = 3.5). An activity grading (Ca,mean = 3) with Ca,initial = 2.2 until Tmax of 240 °C is reached at z = 2.2 m and then a stepwise rise to Ca of 4 in the remaining 9.8 m leads to XCO,per pass of 49%, the maximum for the given conditions.

Graphical abstract: Improvement of a multi-tubular Fischer–Tropsch reactor with gas recycle by appropriate combination of axial activity distribution and gas velocity

Supplementary files

Article information

Article type
Paper
Submitted
18 Jan 2023
Accepted
03 Mar 2023
First published
03 Mar 2023

Catal. Sci. Technol., 2023,13, 2212-2222

Improvement of a multi-tubular Fischer–Tropsch reactor with gas recycle by appropriate combination of axial activity distribution and gas velocity

C. Kern and A. Jess, Catal. Sci. Technol., 2023, 13, 2212 DOI: 10.1039/D3CY00093A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements