Issue 48, 2023
From the journal:

Chemical Communications

Circularly polarized luminescence and nonlinear optical harmonic generation based on chiral zinc halides†

Xiao Han,a   Puxin Cheng,a   Wenqing Han,a   Rongchao Shi,a   Junjie Guan,a   Geng Lib  and  Jialiang Xu ORCID logo *a  

* Corresponding authors

a School of Materials Science and Engineering, Smart Sensing Interdisciplinary Science Center, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tongyan Road 38, Tianjin 300350, P. R. China
E-mail: jialiang.xu@nankai.edu.cn

b National Supercomputer Center in Tianjin, Tianjin 300457, China

Abstract

Chiral hybrid metal halides have grabbed extensive attention in linear and nonlinear chiroptics. Herein, 0D chiral zinc halides, (R-/S-2-MP)ZnCl4, have been fabricated, which demonstrate high efficiency second-order nonlinear optical responses. Incorporating Sb3+ into the chiral zinc halide matrix triggers the circularly polarized luminescence effectively with a balance between quantum yield and luminescence dissymmetry factor.

Graphical abstract: Circularly polarized luminescence and nonlinear optical harmonic generation based on chiral zinc halides

  • This article is part of the themed collection: Perovskites
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Article information

DOI
https://doi.org/10.1039/D3CC01461D
Article type
Communication
Submitted
25 Mar 2023
Accepted
23 May 2023
First published
23 May 2023

Chem. Commun., 2023,59, 7447-7450

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Circularly polarized luminescence and nonlinear optical harmonic generation based on chiral zinc halides

X. Han, P. Cheng, W. Han, R. Shi, J. Guan, G. Li and J. Xu, Chem. Commun., 2023, 59, 7447 DOI: 10.1039/D3CC01461D

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