SCHEDULED MAINTENANCE
A Li-rich strategy towards advanced Mn-doped triphylite cathodes for Li-ion batteries†
Abstract
Triphylite-structured lithium iron/manganese phosphates have captured rapt attention as prospective positive electrodes for Li-ion batteries, targeted to automotive applications. Here we report on a strategy to improve the power characteristics of Mn-doped LiFePO4 cathode materials by introducing extra Li at the transition metal site (Li-rich) via a facile solvothermal synthesis route. The crystal structure refinement based on joint synchrotron and neutron powder diffraction data unambiguously confirmed the formation of a Li-rich phase, with additional validation coming from scanning transmission electron microscopy, electron energy loss spectroscopy, and 57Fe Mössbauer spectroscopy. The particularly created defect structure of the Li-rich Li1+δ(Fe0.5Mn0.5)1−δPO4 with additional Li+ ions residing at the 3d-metal site enables the extended solid solution region of the Li ion de/intercalation mechanism established using operando synchrotron X-ray powder diffraction. The suggested strategy offers an advanced electrochemical behavior of the materials that exhibit specific capacities of over 158 mAh g−1 at C/10 and 120 mAh g−1 at 10C, with retention of 84 ± 4% after 500 cycles at 10C.
- This article is part of the themed collection: Lithium ion batteries – Topic Highlight
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