Issue 42, 2021

Direct conversion of sulfinamides to thiosulfonates without the use of additional redox agents under metal-free conditions

Abstract

Direct conversion of sulfinamides to thiosulfonates is described. Without the use of additional redox agents, the reaction proceeds smoothly in the presence of TFA under metal-free conditions. This protocol possesses many advantages such as odourless and stable starting materials, broad substrate scope, selective synthesis, and mild reaction conditions.

Graphical abstract: Direct conversion of sulfinamides to thiosulfonates without the use of additional redox agents under metal-free conditions

Supplementary files

Article information

Article type
Paper
Submitted
01 Sep 2021
Accepted
27 Sep 2021
First published
29 Sep 2021

Org. Biomol. Chem., 2021,19, 9291-9298

Direct conversion of sulfinamides to thiosulfonates without the use of additional redox agents under metal-free conditions

Y. Ji, C. Zhang, J. Wang, H. Li and Y. Wu, Org. Biomol. Chem., 2021, 19, 9291 DOI: 10.1039/D1OB01714D

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