Issue 74, 2019
From the journal:

Chemical Communications

Synergy of anodic oxidation and cathodic reduction leads to electrochemical deoxygenative C2 arylation of quinoline N-oxides†

Yong Yuan, ORCID logo ‡ab   Minbao Jiang,‡ac   Tao Wang, ORCID logo *ac   Yunkui Xiong,ac   Jun Li,ac   Huijiao Guoac  and  Aiwen Lei ORCID logo *ab  

* Corresponding authors

a National Research Center for Carbohydrate Synthesis, Jiangxi Province's Key Laboratory of Chemical Biology, Jiangxi Normal University, Nanchang 330022, P. R. China
E-mail: wangtao@jxnu.edu.cn, aiwenlei@whu.edu.cn

b College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan, Hubei 430072, P. R. China

c College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China

Abstract

The first example of electrochemical deoxygenative C2 arylation of quinoline N-oxides using sulfonyl hydrazines was demonstrated in this work. By employing both anodic oxidation and cathodic reduction, a variety of 2-arylquinolines were synthesized under metal catalyst-, exogenous-oxidant-, and exogenous-reductant-free conditions.

Graphical abstract: Synergy of anodic oxidation and cathodic reduction leads to electrochemical deoxygenative C2 arylation of quinoline N-oxides

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Article information

DOI
https://doi.org/10.1039/C9CC05841A
Article type
Communication
Submitted
27 Jul 2019
Accepted
15 Aug 2019
First published
28 Aug 2019

Chem. Commun., 2019,55, 11091-11094

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Synergy of anodic oxidation and cathodic reduction leads to electrochemical deoxygenative C2 arylation of quinoline N-oxides

Y. Yuan, M. Jiang, T. Wang, Y. Xiong, J. Li, H. Guo and A. Lei, Chem. Commun., 2019, 55, 11091 DOI: 10.1039/C9CC05841A

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