Issue 74, 2016

Giant room temperature elastocaloric effect of PbTiO3 ferroelectric materials with 90° domain structure

Abstract

The influence of domain structures and domain switching on the elastocaloric effect in PbTiO3 (PTO) with 90° domain structure under the applied stress field at room temperature has been studied using a phase field model. The calculation results indicate that both positive and negative elastocaloric effects can be obtained depending on the directions of the applied stress. The adiabatic temperature change (ΔTσ) almost linearly increases with increase of the applied uniaxial stress fields, and the largest value of negative ΔTσ is about −3.8 K which was obtained at the tensile stress field of about 2 GPa. Moreover, a negative ΔTσ with the magnitude of −7.2 K can be obtained by controlled polarization switching under the applied stress fields. These results provide an efficient way to obtain a large elastocaloric effect in ferroelectric materials through domain engineering at room temperature.

Graphical abstract: Giant room temperature elastocaloric effect of PbTiO3 ferroelectric materials with 90° domain structure

Article information

Article type
Paper
Submitted
19 May 2016
Accepted
15 Jul 2016
First published
18 Jul 2016

RSC Adv., 2016,6, 70557-70562

Giant room temperature elastocaloric effect of PbTiO3 ferroelectric materials with 90° domain structure

F. Wang, B. Li, Y. Ou, L. F. Liu, C. Z. Peng, Z. S. Wang and W. Wang, RSC Adv., 2016, 6, 70557 DOI: 10.1039/C6RA13030E

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