SCHEDULED MAINTENANCE
A facile preparation of superhydrophobic and oleophilic precipitated calcium carbonate sorbent powder for oil spill clean-ups from water and land surfaces†
Abstract
Fabrication of superhydrophobic and oleophilic materials has attracted environment scientists due their application in oil spill clean-up. Herein, we report the preparation of superhydrophobic and oleophilic precipitated calcium carbonate sorbent via a simple and economical one-step synthetic approach using precipitated calcium carbonate as the substrate and palmitic acid as the surface modifying agent. The material is tested for its selectivity and effectiveness in the removal of spilled oil from both water and land surfaces. Test confirms the superhydrophobic character of the material with a static water contact angle of 166 ± 1°, whereas the oleophilic nature was validated from various oil uptake studies. In addition to being superhydrophobic and oleophilic, the sorbent material was found to be reusable for more than five times. Interestingly, the sorbent has high oil sorption selectivity, suitable buoyancy to float on water and possesses high oil sorption efficiencies (>99%).
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