Issue 44, 2014
From the journal:

RSC Advances

Ruthenium catalyzed regioselective coupling of terminal alkynes, amine and carbon dioxide leading to anti-Markovnikov adducts†

Rahul A. Watilea  and  Bhalchandra M. Bhanage*a  

* Corresponding authors

a Department of Chemistry, Institute of Chemical Technology, Matunga, Mumbai, India
E-mail: bm.bhanage@gmail.com, bm.bhanage@ictmumbai.edu.in
Fax: +91 22 3361 1020
Tel: +91 22 3361 1111/2222

Abstract

RuCl2(p-cymene)/DPPE catalyzed addition of secondary amines and CO2 to terminal alkynes affording anti-Markovnikov adducts of vinyl carbamates in good yield with excellent regioselectivity is reported. The catalyst, consisting of labile p-cymene displays very high regioselectivity towards the anti-Markovnikov adducts and was applicable to a variety of aliphatic/aromatic alkynes and secondary amines.

Graphical abstract: Ruthenium catalyzed regioselective coupling of terminal alkynes, amine and carbon dioxide leading to anti-Markovnikov adducts

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4RA03836C
Article type
Communication
Submitted
26 Apr 2014
Accepted
14 May 2014
First published
14 May 2014

RSC Adv., 2014,4, 23022-23026

Author version available

Download author version (PDF)

Permissions

Request permissions

Ruthenium catalyzed regioselective coupling of terminal alkynes, amine and carbon dioxide leading to anti-Markovnikov adducts

R. A. Watile and B. M. Bhanage, RSC Adv., 2014, 4, 23022 DOI: 10.1039/C4RA03836C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements