Issue 31, 2014

Tandem metal relay catalysis: from cyclopropene to polysubstituted furan

Abstract

Transmetalation is a key step in traditional coupling reactions. Herein we discuss the most recent progress in the metal–metal relay catalysis based on a transmetalation strategy. An efficient synthetic strategy for the formation of polysubstituted furan derivatives from cyclopropenes based on the tandem metal relay catalysis (TMRC reaction) is summarized.

Graphical abstract: Tandem metal relay catalysis: from cyclopropene to polysubstituted furan

Article information

Article type
Perspective
Submitted
13 May 2014
Accepted
06 Jun 2014
First published
09 Jun 2014

Org. Biomol. Chem., 2014,12, 5802-5806

Author version available

Tandem metal relay catalysis: from cyclopropene to polysubstituted furan

C. Song, J. Wang and Z. Xu, Org. Biomol. Chem., 2014, 12, 5802 DOI: 10.1039/C4OB00987H

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