Issue 3, 2014

Investigation on combustion derived BaMgAl10O17:Eu2+ phosphor powder and its corresponding PVP/BaMgAl10O17:Eu2+ nanocomposite

Abstract

This work focuses on the study of BaMgAl10O17:Eu2+ (BAM:Eu) nanophosphors prepared by a microwave-assisted combustion procedure and more especially on the polymer/BAM:Eu nanocomposite film suitable for optical devices such as solid-state-lighting. Powder presented a specific nanomorphology, highly friable and thus easily ground into fine particles. They were then homogeneously dispersed into a polymer solution (poly(N-vinylpyrrolidone) or PVP) to elaborate a polymer phosphor nanocomposite. The structural, morphological and optical features of the nanocomposite film have been studied and compared to those of a pristine PVP film and BAM:Eu powder. All the characterizations (XRD, SEM, SAXS, etc.) proved that the blue phosphor nanoparticles are well incorporated into the polymer nanocomposite film which exhibited the characteristic blue emission of Eu2+ under UV light excitation. Furthermore, the photostability of the polymer/phosphor nanocomposite film has been studied after exposure to accelerated artificial photoageing at wavelengths above 300 nm.

Graphical abstract: Investigation on combustion derived BaMgAl10O17:Eu2+ phosphor powder and its corresponding PVP/BaMgAl10O17:Eu2+ nanocomposite

Supplementary files

Article information

Article type
Paper
Submitted
15 Jul 2013
Accepted
09 Oct 2013
First published
10 Oct 2013

Dalton Trans., 2014,43, 1072-1081

Investigation on combustion derived BaMgAl10O17:Eu2+ phosphor powder and its corresponding PVP/BaMgAl10O17:Eu2+ nanocomposite

N. Pradal, G. Chadeyron, S. Thérias, A. Potdevin, C. V. Santilli and R. Mahiou, Dalton Trans., 2014, 43, 1072 DOI: 10.1039/C3DT51915E

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