Issue 3, 2014

Imine hydrogenation by alkylaluminum catalysts

Abstract

Di-isobutylaluminum hydride and tri-iso-butylaluminum (DIBAL 1, TIBAL 2) are shown to be efficient hydrogenation catalysts for a variety of imines at 100 °C and 100 atm of H2, operating via a hydroalumination/hydrogenolysis mechanism.

Graphical abstract: Imine hydrogenation by alkylaluminum catalysts

Supplementary files

Article information

Article type
Communication
Submitted
14 Oct 2013
Accepted
08 Nov 2013
First published
11 Nov 2013

Chem. Commun., 2014,50, 301-303

Imine hydrogenation by alkylaluminum catalysts

J. A. Hatnean, J. W. Thomson, P. A. Chase and D. W. Stephan, Chem. Commun., 2014, 50, 301 DOI: 10.1039/C3CC47889K

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