A neat and high yield chemoselective epoxidation of alkene moieties present in tertiary amines is accomplished by treatment of the corresponding amine–boron trifluoride adduct with dimethyldioxirane or methyl(trifluoromethyl)dioxirane.
M. Ferrer, F. Sánchez-Baeza, A. Messeguer, A. Diez and M. Rubiralta, J. Chem. Soc., Chem. Commun., 1995, 293 DOI: 10.1039/C39950000293
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