Issue 21, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Polynuclear nickel(II) complexes of N4O2- and N4S2-compartmental macrocycles: the structures of a Ni4O4 cubane cluster and the binuclear nickel(II) complex of a benzenethiolate macrocycle

Andrew J. Atkins,   Alexander J. Blake  and  Martin Schröder  

Abstract

The tetranuclear cluster [{Ni2(L1)(MeCO2)}2]2+(L1= the dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylphenol) shows a distorted Ni4O4cubane structure consisting of octahedral nickel(II) centre; the structure of the dithiolate analogue [Ni2(L2)](PF6)2·2dmf (L2= the dianion of the condensation product of 1,3- diaminopropane and 2,6-diformyl-4-methylbenzenethiol;dmf = dimethylformamide)shows square-planar coordination at nickel(II).

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Article information

DOI
https://doi.org/10.1039/C39930001662
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1662-1665

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Polynuclear nickel(II) complexes of N4O2- and N4S2-compartmental macrocycles: the structures of a Ni4O4 cubane cluster and the binuclear nickel(II) complex of a benzenethiolate macrocycle

A. J. Atkins, A. J. Blake and M. Schröder, J. Chem. Soc., Chem. Commun., 1993, 1662 DOI: 10.1039/C39930001662

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