Issue 17, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

A simple synthesis of tetrahydrofuran complexes of lanthanoid trichlorides: convenient substitutes for anhydrous lanthanoid chlorides

Glen B. Deacon,   Tiecheng Feng,   Siegbert Nickel,   Brian W. Skelton  and  Allan H. White  

Abstract

Reaction of lanthanoid metals with hexachloroethane in tetrahydrofuran under ultrasonication conditions gives LnCl3(thf)n(Ln = La, Nd, Sm, n= 2; Ln = Gd, Yb, n= 3; Ln = Er, n= 3.5, thf = tetrahydrofuran) in good yield; the X-ray crystal structure of [YbCl3(thf)2]2, derived from YbCl3(thf)3 by prolonged treatment with pentane, reveals a chloride-bridged octahedral dimer with trans thf ligands.

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Article information

DOI
https://doi.org/10.1039/C39930001328
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1328-1329

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A simple synthesis of tetrahydrofuran complexes of lanthanoid trichlorides: convenient substitutes for anhydrous lanthanoid chlorides

G. B. Deacon, T. Feng, S. Nickel, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1993, 1328 DOI: 10.1039/C39930001328

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