Issue 18, 1992

Luminescent pH sensors based on di(2,2′-bipyridyl)(5,5′-diaminomethyl-2,2′-bipyridyl)-ruthenium(II) complexes

Abstract

Luminescent pH sensors based on [RuII(bpy)3]2+(bpy = 2,2′-bipyridyl) display proton assisted retrieval of luminescence in 1bd and proton assisted quenching of luminescence in 1a(both due to photoinduced electron transfer) and proton promoted luminescence quenching due to the generation of positive charges in the vicinity of the [RuII(bpy)3]2+ luminophore in 1eg probably leading to a Ru–N bond fission in the excited state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1300-1302

Luminescent pH sensors based on di(2,2′-bipyridyl)(5,5′-diaminomethyl-2,2′-bipyridyl)-ruthenium(II) complexes

R. Grigg and W. D. J. A. Norbert, J. Chem. Soc., Chem. Commun., 1992, 1300 DOI: 10.1039/C39920001300

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements