Issue 8, 1987

2-Dimethylaminomethyl-3-trimethylsilylmethylbuta-1,3-diene as a synthetic equivalent of 2,2′-biallyl zwitterionic species

Abstract

The title compound reacts with nucleophiles followed by electrophiles in tandem or in the reverse order smoothly to give 1,2-dimethylenecyclohexanes and their oxa analogues; thus this reagent acts as the synthetic equivalent of 2,2′-biallyl zwitterionic species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 570-571

2-Dimethylaminomethyl-3-trimethylsilylmethylbuta-1,3-diene as a synthetic equivalent of 2,2′-biallyl zwitterionic species

A. Hosomi, K. Hoashi, S. Kohra, Y. Tominaga, K. Otaka and H. Sakurai, J. Chem. Soc., Chem. Commun., 1987, 570 DOI: 10.1039/C39870000570

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