Titanium pentamethylcyclopentadienyl trialkyls (η5-C5Me5)TiR3(R = Me, CH2SiMe3, C6F5, and CH2Ph) are easily obtained by conventional alkylation of the trichloro analogue; the structure of the tribenzyl derivative, determined by X-ray methods, shows some evidence of a CH2⋯ Ti interaction.
M. Mena, M. A. Pellinghelli, P. Royo, R. Serrano and A. Tiripicchio, J. Chem. Soc., Chem. Commun., 1986, 1118 DOI: 10.1039/C39860001118
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