Issue 24, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Weak intermetallic bonding in unusual trinuclear complexes: crystal structure of [Rh3(µ3-tz)(µ2-Cl)Cl(η4-tfb)(CO)4]·½CH2Cl2 and [Rh3(µ3-tz)(µ2-Cl)Cl(η3-C3H5)2(CO)4]·½C2H4Cl2(Htz = 1,2,4-triazole; tfb = tetrafluorobenzonarrelene: 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene)

Luis A. Oro,   M. Teresa Pinillos,   Cristina Tejel,   Concha Focesfoces  and  Felix H. Cano  

Abstract

[Rh(acac)L2][Hacac = acetylacetone; L2=η4-tfb (tetrafluorobenzobarrelene),L =η3-c3H5] react with 1,2,4-triazole (Htz) and [RhCl(CO)2]2 to give trinuclear complexes of formula [Rh3(µ3-tz)(µ2-cl)ClL2(co)4]whose crystal structures, determined by X-ray methods, show intermetallic Rh–Rh distances of 3.425(4) and 3.393(1)Å, respectively.

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Article information

DOI
https://doi.org/10.1039/C39840001687
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1687-1688

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Weak intermetallic bonding in unusual trinuclear complexes: crystal structure of [Rh3(µ3-tz)(µ2-Cl)Cl(η4-tfb)(CO)4]·½CH2Cl2 and [Rh3(µ3-tz)(µ2-Cl)Cl(η3-C3H5)2(CO)4]·½C2H4Cl2(Htz = 1,2,4-triazole; tfb = tetrafluorobenzonarrelene: 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene)

L. A. Oro, M. T. Pinillos, C. Tejel, C. Focesfoces and F. H. Cano, J. Chem. Soc., Chem. Commun., 1984, 1687 DOI: 10.1039/C39840001687

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