Issue 2, 2013
From the journal:

Green Chemistry

Straightforward heterogeneous palladium catalyzed synthesis of aryl ethers and aryl amines via a solvent free aerobic and non-aerobic dehydrogenative arylation†

Marc Sutter,a   Nicolas Sotto,a   Yann Raoul,b   Estelle Métaya  and  Marc Lemaire*a  

* Corresponding authors

a Laboratoire de Catalyse et Synthèse et Environnement, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS), CNRS, UMR5246, Université Lyon 1, 43 Boulevard du 11 Novembre 1918, Bat CPE, Villeurbanne, France
E-mail: marc.lemaire.chimie@univ-lyon1.fr
Fax: +33-472-43-14-08
Tel: +33-472-43-14-07

b Sofiprotéol, 11, rue de Monceau, CS 60003, 75378 Paris Cedex 08, France
E-mail: sofiproteol@prolea.com
Fax: +33 147 230 288
Tel: +33 140 694 800

Abstract

Aryl ethers have been prepared from cyclohexanone derivatives and various alcohols in the presence of a catalytic amount of palladium on charcoal. The formation of an enol ether followed by an aerobic or non-aerobic dehydrogenation reaction, seem to be the key steps of this transformation. In addition, this new method was also adapted for the synthesis of arylamines.

Graphical abstract: Straightforward heterogeneous palladium catalyzed synthesis of aryl ethers and aryl amines via a solvent free aerobic and non-aerobic dehydrogenative arylation

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Article information

DOI
https://doi.org/10.1039/C2GC36776A
Article type
Communication
Submitted
25 Oct 2012
Accepted
16 Nov 2012
First published
19 Nov 2012

Green Chem., 2013,15, 347-352

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Straightforward heterogeneous palladium catalyzed synthesis of aryl ethers and aryl amines via a solvent free aerobic and non-aerobic dehydrogenative arylation

M. Sutter, N. Sotto, Y. Raoul, E. Métay and M. Lemaire, Green Chem., 2013, 15, 347 DOI: 10.1039/C2GC36776A

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