Issue 16, 2004
From the journal:

Chemical Communications

Azines possessing strong push–pull donors/acceptors†

Dharinee D. Choytun,a   Lisa D. Langlois,a   Thomas P. Johansson,a   Charles L. B. Macdonald,*b   Gary W. Leach,a   Noham Weinberga  and  Jason A. C. Clyburne*a  

* Corresponding authors

a Department of Chemistry, Simon Fraser University, Burnaby BC, Canada
E-mail: clyburne@sfu.ca

b Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Ave, Windsor ON, Canada

Abstract

Azines (R2C[double bond, length as m-dash]N–N[double bond, length as m-dash]CR2) are 2,3-diaza analogues of 1,3-butadiene. In this report we show that strong polarisation of the azine imparts structural features consistent with delocalization within the azine fragment; NLO properties for the azines are also reported.

Graphical abstract: Azines possessing strong push–pull donors/acceptors

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Article information

DOI
https://doi.org/10.1039/B404129A
Article type
Communication
Submitted
17 Mar 2004
Accepted
02 Jun 2004
First published
23 Jul 2004

Chem. Commun., 2004, 1842-1843

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Azines possessing strong push–pull donors/acceptors

D. D. Choytun, L. D. Langlois, T. P. Johansson, C. L. B. Macdonald, G. W. Leach, N. Weinberg and J. A. C. Clyburne, Chem. Commun., 2004, 1842 DOI: 10.1039/B404129A

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