Issue 6, 2004
From the journal:

Chemical Communications

Helical supramolecular host with aquapores anchoring alternate molecules of helical water chains†‡

Arindam Mukherjee,a   Manas K. Saha,a   Munirathinam Nethajia  and  Akhil R. Chakravarty*a  

* Corresponding authors

a Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore-560012, India
E-mail: arc@ipc.iisc.ernet.in

Abstract

Unprecedented 1D helical chains of hydrogen bonded water molecules, showing both handedness and anchored onto a helical supramolecular host formed from the self assembly of a dicopper(II) complex (1) containing pentadentate Schiff base (L) and p-hydroxycinnamate in 1·2H2O, propagate along the crystallographic 21-screw axis and the compound shows two endotherms due to loss of water molecules at 61.5 and 88.5 °C in the differential scanning calorimetry giving an overall change of enthalpy value of ∼36 kJ mol−1 per water molecule.

Graphical abstract: Helical supramolecular host with aquapores anchoring alternate molecules of helical water chains

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B316275C
Article type
Communication
Submitted
12 Dec 2003
Accepted
20 Jan 2004
First published
12 Feb 2004

Chem. Commun., 2004, 716-717

Permissions

Request permissions

Helical supramolecular host with aquapores anchoring alternate molecules of helical water chains

A. Mukherjee, M. K. Saha, M. Nethaji and A. R. Chakravarty, Chem. Commun., 2004, 716 DOI: 10.1039/B316275C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements