Issue 9, 2003
From the journal:

Chemical Communications

Electrocatalytic dimerisation of non-heteroatom-substituted manganese alkynylcarbene complexes†

Yannick Ortin,a   Alix Sournia-Saquet,a   Noël Lugan*a  and  René Mathieua  

* Corresponding authors

a Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France
E-mail: lugan@lcc-toulouse.fr
Fax: +33 5 61 55 30 03
Tel: +33 5 61 33 31 71

Abstract

Upon controlled potential electrolysis (−1.30 V vs. SCE), the alkynylcarbene complexes MeCp(CO)2Mn[double bond, length as m-dash]C(R)C[triple bond, length as m-dash]CR′ are seen to undergo an electrocatalytic dimerisation by coupling of the remote alkynyl carbon atoms to afford the ene-diyne dimanganese complexes [MeCp(CO)2Mn]2[η4-(E)-RC[triple bond, length as m-dash]C(R′)C[double bond, length as m-dash]C(R′)C[triple bond, length as m-dash]CR].

Graphical abstract: Electrocatalytic dimerisation of non-heteroatom-substituted manganese alkynylcarbene complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B300623A
Article type
Communication
Submitted
16 Jan 2003
Accepted
17 Mar 2003
First published
02 Apr 2003

Chem. Commun., 2003, 1060-1061

Permissions

Request permissions

Electrocatalytic dimerisation of non-heteroatom-substituted manganese alkynylcarbene complexes

Y. Ortin, A. Sournia-Saquet, N. Lugan and R. Mathieu, Chem. Commun., 2003, 1060 DOI: 10.1039/B300623A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements