Issue 23, 2002
From the journal:

Chemical Communications

A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked, hydroxo-bridged dinuclear zinc complex†

Vivek V. Karambelkar,a   Divya Krishnamurthy,a   Charlotte L. Stern,b   Lev N. Zakharov,c   Arnold L. Rheingoldc  and  David P. Goldberg*a  

* Corresponding authors

a Department of Chemistry, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, Maryland, USA
E-mail: dpg@jhu.edu

b X-ray Crystallography Facility, Northwestern University, Evanston, Illinois, USA

c Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, USA

Abstract

The new sterically encumbered, tripodal N2S(alkylthiolate) ligand, LIm2SH, has been synthesized and used to prepare [(LIm2S)ZnCH3], which upon protonolysis under acidic conditions leads to the synthesis of a novel dinucleating ligand and a zinc dimer with an unusual structure.

Graphical abstract: A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked, hydroxo-bridged dinuclear zinc complex

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Article information

DOI
https://doi.org/10.1039/B207770A
Article type
Communication
Submitted
08 Aug 2002
Accepted
08 Oct 2002
First published
28 Oct 2002

Chem. Commun., 2002, 2772-2773

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A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked, hydroxo-bridged dinuclear zinc complex

V. V. Karambelkar, D. Krishnamurthy, C. L. Stern, L. N. Zakharov, A. L. Rheingold and D. P. Goldberg, Chem. Commun., 2002, 2772 DOI: 10.1039/B207770A

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