Issue 17, 2002
From the journal:

Chemical Communications

Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

Shunichi Fukuzumi,*a   Hironori Kitaguchi,a   Tomoyoshi Suenobua  and  Seiji Ogoa  

* Corresponding authors

a Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation (JST), Suita, Osaka, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp

Abstract

Electron transfer reduction of p-benzoquinones by cobalt tetraphenylporphyrin is enhanced significantly by the presence of o-bis(phenylcarbamoylmethyl)benzene (o-L) due to the regioselective hydrogen bond formation between the corresponding semiquinone radical anions and o-L, whereas m- and p-isomers (m-L and p-L) have no effect on the electron transfer equilibrium or the rate.

Graphical abstract: Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

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Article information

DOI
https://doi.org/10.1039/B205517A
Article type
Communication
Submitted
07 Jun 2002
Accepted
22 Jul 2002
First published
05 Aug 2002

Chem. Commun., 2002, 1984-1985

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Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation

S. Fukuzumi, H. Kitaguchi, T. Suenobu and S. Ogo, Chem. Commun., 2002, 1984 DOI: 10.1039/B205517A

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