Issue 1, 2002
From the journal:

Chemical Communications

Total synthesis and determination of the stereochemistry of 2-amino-3-cyclopropylbutanoic acid, a novel plant growth regulator isolated from the mushroom Amanita castanopsidis Hongo

Yoshiki Morimoto,*a   Mamoru Takaishi,a   Takamasa Kinoshita,a   Kazuhiko Sakaguchib  and  Kozo Shibata†a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka, Japan.
E-mail: morimoto@sci.osaka-cu.ac.jp

b Department of Material Science, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka, Japan

Abstract

The unknown stereostructure of 2-amino-3-cyclopropylbutanoic acid 1, a novel plant growth regulator isolated from the mushroom Amanita castanopsidis Hongo, was determined to be (2S,3S)-2 through its racemic and enantioselective syntheses employing the chelate–enolate Claisen rearrangement as a key step.

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Article information

DOI
https://doi.org/10.1039/B108752E
Article type
Communication
Submitted
27 Sep 2001
Accepted
14 Nov 2001
First published
14 Dec 2001

Chem. Commun., 2002, 42-43

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Total synthesis and determination of the stereochemistry of 2-amino-3-cyclopropylbutanoic acid, a novel plant growth regulator isolated from the mushroom Amanita castanopsidis Hongo

Y. Morimoto, M. Takaishi, T. Kinoshita, K. Sakaguchi and K. Shibata, Chem. Commun., 2002, 42 DOI: 10.1039/B108752E

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