Issue 4, 2000
From the journal:

Green Chemistry

Wacker reaction in supercritical carbon dioxide

Huanfeng Jiang,*a   Lanqi Jiaa  and  Jinheng Lia  

* Corresponding authors

a LCLC, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou, China.
E-mail: jhf@mail.gic.ac.cn

Abstract

It is reported for the first time that the Wacker reaction can be carried out smoothly in supercritical carbon dioxide or ROH/supercritical carbon dioxide. Results show that both scCO2 and co-solvent can remarkably affect the selectivity towards methyl ketone and the presence of ROH accelerates the reaction.The mechanism of the Wacker reaction in scCO2 is also discussed.

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Article information

DOI
https://doi.org/10.1039/B002491K
Article type
Paper
Submitted
29 Mar 2000
First published
20 Jun 2000

Green Chem., 2000,2, 161-164

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Wacker reaction in supercritical carbon dioxide

H. Jiang, L. Jia and J. Li, Green Chem., 2000, 2, 161 DOI: 10.1039/B002491K

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