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Improving the Soundness of Al–Mg-Based Castings Through Chemical Inoculation and Process Optimization

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Abstract

Al–Mg-based alloys are non-heat treatable alloys with an excellent combination of specific strength and ductility, thus having a great potential for automotive applications. However, they suffer from poor castability due to a long freezing range and high oxidation tendency, which makes it challenging to obtain sound castings through shape casting. This study aimed to improve the castability of Al–6Mg alloy by adding chemical inoculations and optimizing processing conditions. The results indicated that the addition of a small amount of Al2Ca resulted in a cleaner melt, with a slight increase in flow length. Moreover, the co-addition of Al2Ca and Ti-based inoculants in the Al–6Mg base alloy induced a further increase of ~ 20% in flow length. Similarly, separate or co-addition of Al2Ca and Ti-based inoculants significantly mitigated the hot tearing of the base alloy. The improved castability was attributed to enhanced oxidation resistance and grain refinement. Additionally, these alloys have shown better fluidity when melted and held in an electric furnace than in an induction furnace. The study also revealed that molten aluminum alloys’ cleanliness can be achieved through active degassing or passive degassing, as both processes remove oxide inclusions.

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References

  1. J.E. Hatch, Aluminum: Properties and Physical Metallurgy (ASM, Ohio, 1984), pp.333–338

    Google Scholar 

  2. G.E. Totten, D.S. Mackenzie, Handbook of Aluminum: Physical Metallurgy and Processes (Marcel Dekker Inc., New York, 2003), pp.490–491

    Book  Google Scholar 

  3. J. Campbell, Complete Casting Handbook: Metal Casting Processes, Metallurgy, Techniques and Design, 1st edn. (Elsevier, Oxford, 2011), pp.128–129

    Google Scholar 

  4. M.V. Glazoff, A. Khvan, V.S. Zolotorevsky, N.A. Belov, A.T. Dinsdale, Casting Aluminum Alloys: Their Physical and Mechanical Metallurgy, 2nd edn. (Elsevier, Oxford, 2018), pp.456–457. https://doi.org/10.1016/C2015-0-02446-7

    Book  Google Scholar 

  5. M.A. Zare, R. Taghiabadi, M.H. Ghoncheh, Effect of cooling rate on microstructure and mechanical properties of AA5056 Al-Mg alloy. Int. J. Metalcasting 16, 1533–1543 (2022). https://doi.org/10.1007/s40962-021-00704-6

    Article  CAS  Google Scholar 

  6. M. Okayasu, S. Takeuchi, Mechanical properties of cast Al-Mg5 alloy produced by heated mold continuous casting. Int. J. Metalcasting 12, 298–306 (2018). https://doi.org/10.1007/s40962-017-0163-6

    Article  CAS  Google Scholar 

  7. C.N. Cochran, D.L. Belitskus, D.L. Kinosz, Oxidation of aluminum-magnesium melts in air, oxygen, flue gas, and carbon dioxide. Metall. Trans. B 8, 323–332 (1977). https://doi.org/10.1007/bf02657663

    Article  Google Scholar 

  8. M. Akbarifar, M. Divandari, S.M.A. Boutorabi, S.H. Ha, Y.O. Yoon, S.K. Kim, Characteristic investigation of the as-received samples: nano-oxides in Al–5Mg–Be melt. Int. J. Metalcasting (2022). https://doi.org/10.1007/s40962-022-00773-1

    Article  Google Scholar 

  9. S.H. Ha, Y.O. Yoon, B.H. Kim, H.K. Lim, T.W. Lee, S.H. Lim, S.K. Kim, Oxide scale behavior and surface protection of Al–Mg alloys containing a trace of Ca. Int. J. Metalcasting 13, 121–129 (2019). https://doi.org/10.1007/s40962-018-0234-3

    Article  CAS  Google Scholar 

  10. I.H. Jung, J.K. Lee, S.K. Kim, Mg-Ca alloys produced by reduction of CaO: understanding of ECO-Mg alloy production. Metall. Mater. Trans. 48B, 1073–1078 (2017). https://doi.org/10.1007/s11663-016-0875-7

    Article  CAS  Google Scholar 

  11. S.H. Ha, Y.O. Yoon, N.S. Kim, S.H. Lim, S.K. Kim, Oxide scale behavior and its effect on oxidation resistance in Al alloys containing alkaline earth metal elements. Defect Diffus. Forum 380, 120–123 (2017). https://doi.org/10.4028/www.scientific.net/DDF.380.120

    Article  Google Scholar 

  12. Y.O. Yoon, S.H. Ha, G.Y. Yeom, H.K. Lim, S.K. Kim, Oxidation behavior of Al2Ca added Al-5Mg alloy in the liquid state. TMS Light Met. (2013). https://doi.org/10.1007/978-3-319-65136-1_56

    Article  Google Scholar 

  13. S.H. Ha, Y.O. Yoon, S.K. Kim, Effect of Al2Ca on oxidation resistance and tensile property of Al–5Mg alloy. J. Korea Foundry Soc. 34, 194–199 (2014). https://doi.org/10.7777/jkfs.2014.34.6.194

    Article  Google Scholar 

  14. J. Jeong, J. Im, K. Song, M. Kwon, S.K. Kim, Y.B. Kang, S.H. Oh, Transmission electron microscopy and thermodynamic studies of CaO-added AZ31 Mg alloys. Acta Mater. 61, 3267–3277 (2013). https://doi.org/10.1016/j.actamat.2013.02.015

    Article  CAS  Google Scholar 

  15. M.D. Sabatino, L. Arnberg, S. Rørvik, A. Prestmo, The influence of oxide inclusions on the fluidity of Al–7 wt.% Si alloy. Mater. Sci. Eng. 413–414A, 272–276 (2005)

    Article  Google Scholar 

  16. K. Dahle, P.A. Tøndel, C.J. Paradies, L. Arnberg, Effect of grain refinement on the fluidity of two commercial Al-Si foundry alloys. Metall. Mater. Trans. 27A, 2305–2313 (1996)

    Article  CAS  Google Scholar 

  17. G. Razaz, T. Carlberg, Hot tearing susceptibility of AA3000 aluminum alloy containing Cu, Ti, and Zr. Metall. Mater. Trans. 50A, 38423854 (2019). https://doi.org/10.1007/s11661-019-05290-1

    Article  CAS  Google Scholar 

  18. A.S. Sabau, B.K. Milligan, S. Mirmiran, C. Glaspi, A. Shyam, J.A. Hynes, A.F. Rodriguez, J.A.G. Villarreal, J. Talamantes, Grain refinement effect on the hot-tearing resistance of higher-temperature Al–Cu–Mn–Zr Alloys. Metals 10, 430–448 (2020). https://doi.org/10.3390/met10040430

    Article  CAS  Google Scholar 

  19. M. Easton, H. Wang, J. Grandfield, D. St John, E. Sweet, An analysis of the effect of grain refinement on the hot tearing of aluminium alloys. Mater. Forum 28, 224–229 (2004)

    CAS  Google Scholar 

  20. A.W. Shah, S.H. Ha, B.H. Kim, Y.O. Yoon, H.K. Lim, S.K. Kim, Effect of Si addition on flow behavior in Al-Mg and Al-Mg-Si molten alloys. Metall. Mater. Trans. 51A, 6670–6678 (2020). https://doi.org/10.1007/s11661-020-06052-0

    Article  CAS  Google Scholar 

  21. A.W. Shah, S.H. Ha, B.H. Kim, Y.O. Yoon, H.K. Lim, S.K. Kim, Effect of compositional variation on the microstructural evolution and the castability of Al–Mg–Si ternary alloys. Metall. Mater. Trans. 52A, 3353–3365 (2021). https://doi.org/10.1007/s11661-021-06306-5

    Article  CAS  Google Scholar 

  22. J.K. Lee, S.K. Kim, Effect of CaO composition on oxidation and burning behaviors of AM50 Mg alloy. Trans. Nonferrous Met. Soc. China 21, 23–27 (2011). https://doi.org/10.1016/S1003-6326(11)61054-6

    Article  Google Scholar 

  23. J. Campbell, Entrainment defects. Mater. Sci. Technol. 22, 127–145 (2006). https://doi.org/10.1179/174328406X74248

    Article  CAS  Google Scholar 

  24. D.G. Eskin, L. Katgerman, Mechanical properties in the semi-solid state and hot tearing of aluminium alloys. Prog. Mater Sci. 49, 629–711 (2004). https://doi.org/10.1016/S0079-6425(03)00037-9

    Article  CAS  Google Scholar 

  25. N. Coniglio, C.E. Cross, Mechanisms for solidification crack initiation and growth in aluminum welding. Metall. Mater. Trans. 40A, 2718–2728 (2009). https://doi.org/10.1007/s11661-009-9964-4

    Article  CAS  Google Scholar 

  26. S. Kou, A criterion for cracking during solidification. Acta Mater. 88, 366–374 (2015). https://doi.org/10.1016/j.actamat.2015.01.034

    Article  CAS  Google Scholar 

  27. M. Uludag, R. Cetin, D. Dispinar, Freezing range, melt quality, and hot tearing in Al-Si alloys. Metall. Mater. Trans. 49A, 1948–1961 (2018). https://doi.org/10.1007/s11661-018-4512-8

    Article  CAS  Google Scholar 

  28. J. Campbell, Stop pouring, start casting. Int. J. Metalcasting 6, 7–18 (2012). https://doi.org/10.1007/BF03355529

    Article  CAS  Google Scholar 

  29. M. Pourgharibshahi, H. Saghafian, M. Divandari, F. Golestannejad, A critical conception of hot-tearing susceptibility: shape casting with wrought aluminum alloys. Int. J. Metalcasting 16, 853–870 (2022). https://doi.org/10.1007/s40962-021-00632-5

    Article  Google Scholar 

  30. K. Prapasajchavet, Y. Harada, S. Kumai, Microstructure analysis of Al–5.5at%Mg alloy semi-solid slurry by Weck’s reagent. Int. J. Metalcasting 11, 123–130 (2017). https://doi.org/10.1007/s40962-016-0084-9

    Article  Google Scholar 

  31. A.M. Nabawy, A.M. Samuel, H.W. Doty, F.H. Samuel, A review on the criteria of hot tearing susceptibility of aluminum cast alloys. Int. J. Metalcasting 15, 1362–1374 (2021). https://doi.org/10.1007/s40962-020-00559-3

    Article  Google Scholar 

  32. S. Li, D. Apelian, Hot tearing of aluminum alloys. Int. J. Metalcasting 5, 23–40 (2011). https://doi.org/10.1007/BF03355505

    Article  Google Scholar 

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Correspondence to Abdul Wahid Shah.

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Shah, A.W., Ha, SH., Siddique, J.A. et al. Improving the Soundness of Al–Mg-Based Castings Through Chemical Inoculation and Process Optimization. Inter Metalcast 18, 470–479 (2024). https://doi.org/10.1007/s40962-023-01017-6

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