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RETRACTED ARTICLE: Investigation on Adsorption and the Corrosion Inhibition Effect of Some Novel Hydrazide Derivatives for Mild Steel in HCl Solution

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This article was retracted on 24 July 2018

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Abstract

Two hydrazide derivatives, namely, N′-(thiophene-2-ylmethylene)nicotinic hydrazone (TNH) and N′-(pyrrol-2-ylmethylene)nicotinic hydrazone (PNH), have been synthesized and investigated as corrosion inhibitors for mild steel in 1 M HCl solution by electrochemical, weight loss, field emission–scanning electron microscope (FE-SEM), atomic force microscope (AFM), and quantum chemical calculation methods. The experimental results show that both the compounds are good inhibitors for mild steel in 1 M HCl. They act as mixed type inhibitors with predominating cathodic character. The adsorption of inhibitors obeys the Langmuir adsorption isotherm. Correlation between quantum chemical parameters and experimental results is discussed.

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  • 24 July 2018

    The Principal Editor has retracted this article [1] because Figures 9a, 9b, 9f, 10a, and 10b, as well as significant parts of the text, were duplicated from a previously published article [2]. Authors Dharmendra Kumar Singh and Rohith P. John agree to this retraction; authors Debasis Behera, Mantu Kumar Singh, and G. Udayabhanu have not responded to any correspondence from the editor/publisher about this retraction.

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Acknowledgment

The authors gratefully acknowledge the University Grant Commission, Grant No-PSJ-009/13-14, (ERO), ID NO-JVB3-018, for providing financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry, P.K. Roy Memorial College, Dhanbad, 826004, India

    Dharmendra Kumar Singh

  2. Department of Chemistry, Manipal University, Jaipur, 303007, India

    Debasis Behera

  3. Department of Applied Chemistry, Indian School of Mines, Dhanbad, 826004, India

    Mantu Kumar Singh, G. Udayabhanu & Rohith P. John

Authors
  1. Dharmendra Kumar Singh
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  2. Debasis Behera
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  3. Mantu Kumar Singh
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  4. G. Udayabhanu
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  5. Rohith P. John
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Corresponding author

Correspondence to Dharmendra Kumar Singh.

Additional information

Manuscript submitted October 20, 2016.

The Principal Editor has retracted this article [1] because Figures 9a, 9b, 9f, 10a, and 10b, as well as significant parts of the text, were duplicated from a previously published article [2]. Authors Dharmendra Kumar Singh and Rohith P. John agree to this retraction; authors Debasis Behera, Mantu Kumar Singh, and G. Udayabhanu have not responded to any correspondence from the editor/publisher about this retraction.

1. Investigation on Adsorption and the Corrosion Inhibition Effect of Some Novel Hydrazide Derivatives for Mild Steel in HCl Solution Metallurgical and Materials Transactions A (2017) https://doi.org/10.1007/s11661-017-4247-y Dharmendra Kumar Singh, Debasis Behera, Mantu Kumar Singh, G. Udayabhanu, Rohith P. John

2. 4(N,N-dimethylamino) benzaldehyde nicotinic hydrazone as corrosion inhibitor for mild steel in 1M HCl solution: An experimental and theoretical study Journal of Molecular Liquids (2016) https://doi.org/10.1016/j.molliq.2016.02.012 Dharmendra Kumar Singh, Santosh Kumar, G. Udayabhanu, Rohith P. John

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Singh, D.K., Behera, D., Singh, M.K. et al. RETRACTED ARTICLE: Investigation on Adsorption and the Corrosion Inhibition Effect of Some Novel Hydrazide Derivatives for Mild Steel in HCl Solution. Metall Mater Trans A 48, 5132–5145 (2017). https://doi.org/10.1007/s11661-017-4247-y

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