Abstract
The surface plasmon resonance (SPR) sensor with better sensitivity and gas detection capabilities is reported in this paper. It is based on a hybrid layer of silver (Ag)/magnesium oxide (MgO)/silicon (Si). For numerical analysis, the finite element technique (FEM) was employed. The attenuated total reflection (ATR) approach has been used for diagnosing various types of hazardous gas. The increase in the refractive index of various hazardous gases, ranging from 1.327 to 1.38 for four different types of gas, caused the resonance angle to shift. The obtained sensitivities were 86.12 deg/RIU, 164.54 deg/RIU, 199.59 deg/RIU, and 253.68 deg/RIU, respectively, for cyanogen, phosgene, ethanol, and propane gas. Additionally, the values of the detection accuracy (DA), the figure of merits (FoM), and full-width at half-maximum (FWHM), which are 0.17 deg−1, 43.30 RIU−1, and 5.86 deg, respectively, were also obtained. The proposed structure’s distribution of the electric field propagation under resonant conditions was also depicted. Further tests were done to see how the thickness of the Ag and other layers affected the overall sensitivity sensor for the four different gas types. The proposed layered Ag/MgO/Si arrangement had the highest overall sensitivity in distinguishing propane gas from other hazardous gases.
Similar content being viewed by others
Availability of Data and Material
No data available.
Code Availability
Not applicable.
References
Naresh V, Lee N (2021) A review on biosensors and recent development of nanostructured materials-enabled biosensors. Sensors (Switzerland) 21(4):1–35. https://doi.org/10.3390/s21041109
Uniyal A, Srivastava G, Pal A, Taya S, Muduli A (2023) Recent advances in optical biosensors for sensing applications: a review. Plasmonics 0123456789. https://doi.org/10.1007/s11468-023-01803-2
Kitenge D, Joshi RK, Hirai M, Kumar A (2009) Nanostructured silver films for surface plasmon resonance-based gas sensors. IEEE Sens J 9(12):1797–1801. https://doi.org/10.1109/JSEN.2009.2031168
Raether H (1988) Intro_contents. Intro_surface plasmons on smooth and rough surfaces and on gratings. 78:1988
Nylander C, Liedberg B, Lind T (1982) Gas detection by means of surface plasmon resonance. Sens Actuators 3:79–88. https://doi.org/10.1016/0250-6874(82)80008-5
Karki B, Jha A, Pal A, Srivastava V (2022) Sensitivity enhancement of refractive index-based surface plasmon resonance sensor for glucose detection. Opt Quantum Electron 54(9):1–13. https://doi.org/10.1007/s11082-022-04004-z
Uniyal A et al. (2023) Surface plasmon resonance biosensor sensitivity improvement employing of 2D materials and BaTiO 3 with bimetallic layers of silver. J Mater Sci Mater Electron 466. https://doi.org/10.1007/s10854-023-09821-w
Shivangani et al. (2022) Numerical study to enhance the sensitivity of a surface plasmon resonance sensor with BlueP/WS2-covered Al2 O3-nickel nanofilms. Nanomaterials 12:13. https://doi.org/10.3390/nano12132205
Singh S, Sharma AK, Lohia P, Dwivedi DK (2021) Theoretical analysis of sensitivity enhancement of surface plasmon resonance biosensor with zinc oxide and blue phosphorus/MoS2 heterostructure. Optik (Stuttg) 244:167618. https://doi.org/10.1016/j.ijleo.2021.167618
Chen S, Lin C (2019) Sensitivity comparison of graphene based surface plasmon resonance biosensor with Au, Ag and Cu in the visible region 0–6
Bijalwan A, Rastogi V (2017) Sensitivity enhancement of a conventional gold grating assisted surface plasmon resonance sensor by using a bimetallic configuration. Appl Opt 56(35):9606. https://doi.org/10.1364/ao.56.009606
Shakya AK, Singh S (2023) State of the art alliance of refractive index sensing and spectroscopy techniques for household oils analysis. Plasmonics 1–18
Shakya AK, Singh S (2022) Design of a novel refractive index BIOSENSOR for heavy metal detection from water samples based on fusion of spectroscopy and refractive index sensing. Optik (Stuttg)270:169892
Shakya AK, Singh S (2023) Novel merger of spectroscopy and refractive index sensing for modelling hyper sensitive hexa-slotted plasmonic sensor for transformer oil monitoring in near-infrared region. Opt Quantum Electron 55(9):764
Shakya AK, Singh S (2022) Design of novel Penta core PCF SPR RI sensor based on fusion of IMD and EMD techniques for analysis of water and transformer oil. Measurement 188:110513
Shakya AK, Singh S (2023) Performance analysis of a developed optical sensing setup based on the Beer-Lambert law. Plasmonics 1–9
Shakya AK, Singh S (2022) Design of biochemical biosensor based on transmission, absorbance and refractive index. Biosens Bioelectron X 10:100089
Shakya AK, Singh S (2022) State of the art in fiber optics sensors for heavy metals detection. Opt Laser Technol 153:108246
Singh Y, Kumar M, Sanjeev P, Raghuwanshi K (2021) Sensitivity enhancement of SPR sensor with the black phosphorus and graphene with Bi ‑ layer of gold for chemical sensing. Plasmonics 1781–1790. https://doi.org/10.1007/s11468-020-01315-3
Panda A, Pukhrambam PD (2022) Design and modelling of reconfigurable surface plasmon resonance refractive index sensor employing graphene and Sb2S3 for detection of dengue virus. Phys B Condens Matter 638:413965. https://doi.org/10.1016/j.physb.2022.413965
Almawgani AHM, Sarkar P, Pal A, Srivastava G, Uniyal A (2021) Titanium disilicide, black phosphorus – based surface plasmon resonance sensor for dengue detection. Plasmonics 0123456789. https://doi.org/10.1007/s11468-023-01856-3
Yadav A, Kumar S, Kumar A, Sharan P (2023) Effect of 2-D nanomaterials on sensitivity of plasmonic biosensor for efficient urine glucose detection. Front Mater 9(January):1–12. https://doi.org/10.3389/fmats.2022.1106251
Singh S, Sharma AK, Lohia P, Dwivedi DK, Singh PK (2022) Design and modelling of high-performance surface plasmon resonance refractive index sensor using BaTiO3, MXene and nickel hybrid nanostructure. Plasmonics 17(5):2049–2062. https://doi.org/10.1007/s11468-022-01692-x
Sadri-Moshkenani P et al (2020) Effect of magnesium oxide adhesion layer on resonance behavior of plasmonic nanostructures. Appl Phys Lett 116:24
Verma A, Prakash A, Tripathi R (2016) Sensitivity improvement of graphene based surface plasmon resonance biosensors with chaclogenide prism. Optik (Stuttg) 127(4):1787–1791
Ouyang Q et al (2016) Sensitivity enhancement of transition metal dichalcogenides/silicon nanostructure-based surface plasmon resonance biosensor. Sci Rep 6(March):1–13. https://doi.org/10.1038/srep28190
Srivastava A, Prajapati YK (2019) Performance analysis of silicon and blue phosphorene/MoS2 hetero-structure based SPR sensor. Photonic Sensors 9(3):284–292. https://doi.org/10.1007/s13320-019-0533-1
Chen Y, Ren R, Pu H, Chang J, Mao S, Chen J (2017) Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets. Biosens Bioelectron 89:505–510. https://doi.org/10.1016/j.bios.2016.03.059
Cho SY et al (2016) Superior chemical sensing performance of black phosphorus: comparison with MoS2and graphene. Adv Mater 28(32):7020–7028. https://doi.org/10.1002/adma.201601167
Lee G, Kim S, Jung S, Jang S, Kim J (2017) Suspended black phosphorus nanosheet gas sensors. Sensors Actuators, B Chem 250:569–573. https://doi.org/10.1016/j.snb.2017.04.176
Srivastava A, Verma A, Prajapati YK (2021) Theoretical study of hazardous carbon-di-oxide gas sensing using MIM structure-based SPR sensing scheme. IET Optoelectron 15(4):167–177. https://doi.org/10.1049/ote2.12035
Singh Y, Raghuwanshi SK (2019) Sensitivity enhancement of the surface plasmon resonance gas sensor with black phosphorus. IEEE Sensors Lett 3(12):1–4. https://doi.org/10.1109/LSENS.2019.2954052
Maurya JB, Prajapati YK, Raikwar S, Saini JP (2018) A silicon-black phosphorous based surface plasmon resonance sensor for the detection of NO2 gas. Optik (Stuttg) 160:428–433. https://doi.org/10.1016/j.ijleo.2018.02.002
Srivastava T, Jha R (2018) Black phosphorus: a new platform for gaseous sensing based on surface plasmon resonance. IEEE Photonics Technol Lett 30(4):319–322. https://doi.org/10.1109/LPT.2017.2787057
Wu L et al (2017) Sensitivity enhancement by using few-layer black phosphorus-graphene/TMDCs heterostructure in surface plasmon resonance biochemical sensor. Sensors Actuators, B Chem 249:542–548. https://doi.org/10.1016/j.snb.2017.04.110
Kumar R, Pal S, Verma A, Prajapati YK, Saini JP (2020) Effect of silicon on sensitivity of SPR biosensor using hybrid nanostructure of black phosphorus and MXene. Superlattices Microstruct 145:106591. https://doi.org/10.1016/j.spmi.2020.106591
Almawgani AHM, Daher MG, Taya SA, Mashagbeh M, Colak I (2022) Optical detection of fat concentration in milk using MXene-based surface plasmon resonance structure. Biosensors (12):7. https://doi.org/10.3390/bios12070535
Uniyal A, Chauhan B, Pal A, Tomar S, Uniyal PD (2023) Surface plasmon resonance sensor for enhancement of sensitivity. J Graph Era Univ 11:177–190. https://doi.org/10.13052/jgeu0975-1416.1124
Singh S, Sharma AK, Lohia P, Dwivedi DK, Kumar V, Singh PK (2023) Simulation study of reconfigurable surface plasmon resonance refractive index sensor employing bismuth telluride and MXene nanomaterial for cancer cell detection. Phys Scr 98:2. https://doi.org/10.1088/1402-4896/acb023
Ghorbanpour M (2015) Fabrication of a new amine functionalised bi-layered gold/silver SPR sensor chip. J Phys Sci 26(2):1–10
Ansari G, Pal A, Srivastava AK, Verma G (2023) Detection of hemoglobin concentration in human blood samples using a zinc oxide nanowire and graphene layer heterostructure based refractive index biosensor. Opt Laser Technol 164(2):111. https://doi.org/10.1016/0030-3992(80)90045-6
Homola J, Koudela I, Yee SS (1999) Surface plasmon resonance sensors based on diffraction gratings and prism couplers: sensitivity comparison. Sensors Actuators, B Chem 54(1):16–24. https://doi.org/10.1016/S0925-4005(98)00322-0
Karki B, Uniyal A, Chauhan B, Pal A (2022) Sensitivity enhancement of a graphene, zinc sulfide-based surface plasmon resonance biosensor with an Ag metal configuration in the visible region. J Comput Electron. https://doi.org/10.1007/s10825-022-01854-4
Karki B, Uniyal A, Sarkar P, Pal A, Yadav RB (2023) Sensitivity improvement of surface plasmon resonance sensor for glucose detection in urine samples using heterogeneous layers: an analytical perspective. J Opt1–11
Pandey S, Singh S, Agarwal S, Sharma AK, Lohia P, Dwivedi DK (2022) Simulation study to improve the sensitivity of surface plasmon resonance sensor by using ferric oxide, nickel and antimonene nanomaterials. Optik (Stuttg) 267:169757. https://doi.org/10.1016/j.ijleo.2022.169757
Uniyal A, Pal A, Chauhan B (2022) Long-range Spr sensor employing platinum diselenide and cytop nanolayers giving improved performance. Phys B Condens Matter 649:414487. https://doi.org/10.2139/ssrn.4230023
Uniyal A, Gotam S, Ram T, Chauhan B, Jha A, Pal A (2022) Next generation ultra-sensitive surface plasmon resonance biosensors. In: Khare, N., Tomar, D.S., Ahirwal, M.K., Semwal, V.B., Soni, V. (eds) Machine learning, image processing, network security and data sciences”. MIND 2022. Commun Comput Inf Sci 1762. Springer, Cham. https://doi.org/10.1007/978-3-031-24352-3_31
Uniyal A, Srivastava G, Sarkar P, Kumar M, Singh S (2023) Fluorinated graphene and CNT-based surface plasmon resonance sensor for detecting the viral particles of SARS-CoV-2. Phys B Condens Matter 669:415282. https://doi.org/10.1016/j.physb.2023.415282
Pal A et al. (2023) Detecting binary mixtures of sulfolane with ethylene glycol, diethylene glycol, and polyethylene glycol in water using surface plasmon resonance sensor: a numerical investigation. Plasmonics 1–11
M. S. Rahman, M. S. Anower, M. R. Hasan, and K. A. Rikta, “Sensitivity enhancement of MoS2-graphene hybrid structure based surface plasmon resonance biosensor using air gap,” Sens. Lett., vol. 15, no. 6, pp. 510–516, 2017.
M. S. Rahman, M. S. Anower, M. R. Hasan, M. B. Hossain, and M. I. Haque, “Design and numerical analysis of highly sensitive Au-MoS2-graphene based hybrid surface plasmon resonance biosensor,” Opt. Commun., vol. 396, pp. 36–43, 2017.
A. S. Kushwaha, A. Kumar, R. Kumar, and S. K. Srivastava, “A study of surface plasmon resonance (SPR) based biosensor with improved sensitivity,” Photonics Nanostructures - Fundam. Appl., vol. 31, no. March, pp. 99–106, 2018, doi: 10.1016/j.photonics.2018.06.003.
Funding
The authors are thankful to the Deanship of Scientific Research at Najran University for funding this work under the Research Groups Funding program grant code (NU/RG/SERC/12/3).
Author information
Authors and Affiliations
Contributions
Abdulkarim H. M. Almawgani: conceptualization and software. Arun Uniyal: conceptualization. Partha Sarkar: writing—review and editing. Gaurav Srivastava: writing. Adam R. H. Alhawari: writing—original draft. Gaurav Dhiman: writing—review and editing, response to review preparation. Debashish Pal: formal analysis. Arjuna Muduli: formal analysis. Sandeep Sharma: Supervision. Amrindra Pal: supervision. All authors gave final approval for publication and agreed to be held accountable for the work performed therein.
Corresponding author
Ethics declarations
Ethics Approval
Not applicable. The work presented in this manuscript is mathematical modeling only for the proposed biosensor. No experiment was performed on the human body and living organisms/animals. So, ethical approval from an ethical committee is not required.
Consent to Participate
I am willing to participate in the work presented in this manuscript.
Consent for Publication
The author has given their consent to publish this work.
Conflict of Interest
The author declares no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Almawgani, A.H.M., Uniyal, A., Sarkar, P. et al. Magnesium Oxide and Silicon-Assisted Surface Plasmon Resonance Sensor for Gas Detection: A Performance Analysis. Plasmonics (2024). https://doi.org/10.1007/s11468-023-02174-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11468-023-02174-4