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Synthesis and characterization of oxo-vanadium complex anchored onto SBA-15 as a green, novel and reusable nanocatalyst for the oxidation of sulfides and oxidative coupling of thiols

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Abstract

The present work describes the synthesis of a new oxo-vanadium complex immobilized on SBA-15 nanostructure as an efficient catalyst for oxidation of sulfides and oxidative coupling of thiols. Characterization of the resultant AMPD@SBA-15 nanostructure was performed by various physico-chemical techniques such as Fourier transform infrared spectroscopy, transmission and scanning electron microscopies, energy-dispersive X-ray spectroscopy, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, thermal gravimetric analysis, and N2 adsorption and desorption. The results of the developed procedure bring several benefits such as the use of commercially available, ecologically benign, operational simplicity, and cheap and chemically inert reagents. It shows good reaction times, practicability and high efficiency, and is easily recovered from the reaction mixture by simple filtration and reused for several consecutive cycles without noticeable change in its catalytic activity. More importantly, high efficiency, simple and an inexpensive procedure, commercially available materials, easy separation, and an eco-friendly procedure are the several advantages of the currently employed heterogeneous catalytic system.

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Acknowledgements

The authors are deeply grateful to Erfan Ghadermazi, University of Kurdistan and Ilam University for financial support of this research project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Taiebeh Tamoradi, Mohammad Ghadermazi & Somayeh Molaei

  2. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Arash Ghorbani-Choghamarani

Authors
  1. Taiebeh Tamoradi
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  2. Mohammad Ghadermazi
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  3. Arash Ghorbani-Choghamarani
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  4. Somayeh Molaei
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Correspondence to Taiebeh Tamoradi, Mohammad Ghadermazi or Arash Ghorbani-Choghamarani.

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Tamoradi, T., Ghadermazi, M., Ghorbani-Choghamarani, A. et al. Synthesis and characterization of oxo-vanadium complex anchored onto SBA-15 as a green, novel and reusable nanocatalyst for the oxidation of sulfides and oxidative coupling of thiols. Res Chem Intermed 44, 4259–4276 (2018). https://doi.org/10.1007/s11164-018-3367-3

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  • DOI: https://doi.org/10.1007/s11164-018-3367-3

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