Issue 24, 2000
From the journal:

Chemical Communications

Immobilisation of ketone catalyst: a method to prevent ketone catalyst from decomposing during dioxirane-mediated epoxidation of alkenes

Choong Eui Song,*a   Jin Seok Lim,b   Su Chang Kim,b   Kee-Jung Leeb  and  Dae Yoon Chic  

* Corresponding authors

a Life Sciences Division, Korea Institute of Science and Technology, PO Box 131, Cheongryang, Seoul, Korea.
E-mail: s1673@kist.re.kr

b Division of Chemical Engineering and Industrial Chemistry, Hanyang University, Seoul, Korea

c Department of Chemistry, Inha University, 253 Yonghyun-Dong, Nam-Ku, Inchon, Korea

Abstract

Covalent attachment of trifluoromethyl ketone catalyst to a solid support such as silica gel increased the stability of catalyst dramatically, so solving an intrinsic problem of dioxirane-mediated epoxidation of alkenes catalysed by ketones.

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Article information

DOI
https://doi.org/10.1039/B005604I
Article type
Communication
Submitted
11 Jul 2000
Accepted
30 Oct 2000
First published
21 Nov 2000

Chem. Commun., 2000, 2415-2416

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Immobilisation of ketone catalyst: a method to prevent ketone catalyst from decomposing during dioxirane-mediated epoxidation of alkenes

C. E. Song, J. S. Lim, S. C. Kim, K. Lee and D. Y. Chi, Chem. Commun., 2000, 2415 DOI: 10.1039/B005604I

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