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Thermophysical Properties of the 2-Methylpropan-1-ol + Cyclohexane + Benzene Ternary System and Its Binary Subsystems Within the Temperature Range (293.15–333.15) K and Under Ambient Pressure

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Abstract

Experimental densities ρ and sound speeds u at temperatures (293.15, 298.15, 303.15, 313.15, 323.15, and 333.15) K and under ambient pressure are reported for the first time for the ternary system (2-methylpropan-1-ol + cyclohexane + benzene) covering the entire composition ranges. The corresponding binary subsystems (2-methylpropan-1-ol + cyclohexane), (2-methylpropan-1-ol + benzene), and (cyclohexane + benzene) have also been studied. The experimental data were used to derive excess thermodynamic properties, namely excess molar volumes \({V}_{m}^{E}\) and excess isentropic compressibilities \({\kappa }_{S}^{E}\). The variation of \({V}_{m}^{E}\) and \({\kappa }_{S}^{E}\) with composition and temperature have been interpreted in terms of molecular interactions between the components of the mixture. The Redlich–Kister polynomial was used to correlate the excess thermodynamic properties of the studied binary mixtures. The Cibulka equation was the mathematical model of choice to correlate the ternary excess properties. Furthermore, the Jouyban–Acree model was used to mathematically represent the density and sound speed of the studied mixtures at different temperatures. The accuracy of the Jouban–Acree model was evaluated, and the absolute average deviation (APD) for density and sound speed of the binary mixtures was less than 0.07 % and 0.21 %, respectively. The APDs for density and sound speed of the ternary mixture were 0.30 % and 0.64 %, respectively.

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Data Availability

The datasets generated during and/or analysed during the current study are available from the corresponding author upon reasonable request.

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Authors and Affiliations

  1. Departamenti i Fizikës, Universiteti i Prishtinës, Rr. Eqrem Çabej nr. 51, Prishtina, Kosovo

    Fisnik Aliaj, Naim Syla & Granita Zenuni

  2. Departmenti i Inxhinierisë Fizike, Universiteti Politeknik i Tiranës, Sheshi Nëna Terezë nr. 4, Tirana, Albania

    Altin Gjevori, Artan Llozana & Arbër Zeqiraj

  3. Departamenti i Kimisë, Universiteti i Prishtinës, Rr. Agim Ramadani nr. 3, Prishtina, Kosovo

    Tahir Arbneshi

  4. Departmenti i Materialeve dhe Metalurgjisë, Universiteti “Isa Boletini” Mitrovicë, Ukshin Kovaçica, Mitrovicë, Kosovo

    Arbër Zeqiraj

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Aliaj, F., Gjevori, A., Llozana, A. et al. Thermophysical Properties of the 2-Methylpropan-1-ol + Cyclohexane + Benzene Ternary System and Its Binary Subsystems Within the Temperature Range (293.15–333.15) K and Under Ambient Pressure. Int J Thermophys 44, 113 (2023). https://doi.org/10.1007/s10765-023-03222-1

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