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Surface decoration of Au–Pt bimetallic inorganic–organic hybrid nanocomposite modified carbon ceramic electrode with vanadium N-salicylidene-L-histidine–al-MCM-41 for electrooxidation of thiosulphate

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Abstract

This work describes the electrochemical behavior of vanadium N-salicylidene-L-histidine-Al-mobil composition of matter no. 41 (MCM-41) (V(His)/Al-MCM-41) film immobilized on the surface of bimetallic Au–Pt inorganic–organic hybrid nanocomposite carbon ceramic electrode and its electrocatalytic activity toward the oxidation of thiosulphate. The surface structure and composition of the sensor was characterized by scanning electron microscopy (SEM). Electrocatalytic oxidation of thiosulphate on the surface of modified electrode was investigated with cyclic voltammetry, chronoamperometry and hydrodynamic amperometric techniques and the results showed that the vanadium film displays excellent electrochemical catalytic activities towards thiosulphate oxidation. The modified electrode indicated reproducible behavior and high level of stability during the electrochemical experiments.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran

    Azadeh Azadbakht, Amir Reza Abbasi, Zohreh Derikvand & Shiba Amraei

Authors
  1. Azadeh Azadbakht
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  2. Amir Reza Abbasi
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  3. Zohreh Derikvand
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  4. Shiba Amraei
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Correspondence to Azadeh Azadbakht.

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The article is published in the original.

Published in Russian in Elektrokhimiya, 2015, Vol. 51, No. 9, pp. 955–970.

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Azadbakht, A., Abbasi, A.R., Derikvand, Z. et al. Surface decoration of Au–Pt bimetallic inorganic–organic hybrid nanocomposite modified carbon ceramic electrode with vanadium N-salicylidene-L-histidine–al-MCM-41 for electrooxidation of thiosulphate. Russ J Electrochem 51, 843–856 (2015). https://doi.org/10.1134/S1023193515090025

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  • DOI: https://doi.org/10.1134/S1023193515090025

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