Abstract
Micropyretic synthesis technique employs self-sustaining exothermic (combustion) reactions for the preparation of various ceramic, intermetallic, and composite materials. In the present work, the combustion reactions of Mo and Si with Al additions have been systematically studied. The atomic mixtures of the reactant powders are chosen to be Mo + (2 − x)Si + xAl with x = 0−0.4. In comparison with the Mo + 2Si reaction which leads to the formation of MoSi2, the substitution of Al for Si decreases the sample ignition temperature, but increases the intensity of the combustion reactions. In addition, the substitution of Al for Si results in the formation of a ternary intermetallic phase, called molybdenum alumino-silicide Mo(Si, Al)2, in the synthesized product. When the content of Al in the reactant mixtures reaches 0.4, nearly single phase Mo(Si, Al)2 is obtained and no MoSi2 is detected in the reaction product. These influences are analyzed by using x-ray diffraction (XRD), scanning electron microscopy (SEM), and differential thermal analysis (DTA). The effect of Al additions on the reaction mechanism is also discussed.
Similar content being viewed by others
References
Z. A. Munir and U. Anselmi-Tamburini, Mater. Sci. Reports 3, 277 (1989).
A. G. Merzhanov, in Combustion and Plasma Synthesis of High-Temperature Materials, edited by Z.A. Munir and J.B. Holt (VCH Publishers, New York, 1990), p. 1.
H. C. Yi and J. J. Moore, J. Mater. Sci. 25, 1159 (1990).
M. Fu and J. A. Sekhar, Key Engineering Materials 108–110, 19 (1995).
A. Bose, B. Moore, R.M. German, and N. S. Stoloff, JOM 40 (9), 14 (1988).
H. P. Li, S. Bhaduri, and J. A. Sekhar, Metall. Trans. A 23A, 251 (1992).
H. P. Li and JA. Sekhar, J. Mater. Res. 8, 2515 (1993).
M. G. Lakshmikantha, A. Bhattacharya, and J. A. Sekhar, Metall. Trans. A 23A, 23 (1992).
M. G. Lakshmikantha and J. A. Sekhar, Metall. Trans. A 24A, 617 (1993).
M. G. Lakshmikantha and J.A. Sekhar, J. Am. Ceram. Soc. 77 (1), 202 (1994).
C. T. Ho and J. A. Sekhar, in High Temperature Ordered Inter-metallic Alloys IV, edited by L. A. Johnson, D. P. Pope, and J.O. Stiegler (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), p. 1057.
J. A. Sekhar, A. K. Bhattacharya, and H. P. Li, U.S. Patent 5 110 688 (1992).
H. P. Li and J.A. Sekhar, in Advanced Synthesis of Engineered Structural Materials, edited by J.J. Moore, E. J. Lavernia, and F. H. Froes (ASM INTERNATIONAL, Materials Park, OH, 1993), p. 25.
H. P. Li and J. A. Sekhar, Mater. Sci. Eng. A160, 221 (1993).
J. A. Sekhar, S. Bhaduri, H. P. Li, and N. S. Canarslan, U.S. Patent 5 188 678 (1993).
J. Subrahmanyam and R. Mohan Rao, Mater. Sci. Eng. A183, 205 (1994).
A. R. Sarkisyan, S. K. Dolukhanyan, I. P. Borovinskaya, and A. G. Merzhanov, Combust. Explos. Shock Waves 14, 310 (1978).
S. Zhang and Z. A. Munir, J. Mater. Sci. 26, 3685 (1991).
S. C. Deevi, J. Mater. Sci. 26, 3343 (1991).
V. N. Bloshenko, V. A. Bokii, and I.P. Borovinskaya, Combust. Explos. Shock Waves 21, 202 (1985).
V. G. Kayuk, M.A. Kuzenkova, S.K. Dolukhanyan, and A.R. Sarkisyan, Sov. Powder Metall. Met. Ceram. 188, 588 (1978).
MHI Element Handbook (1996), Version 6.
H. H. Hausner, Coatings of High-Temperature Materials (Plenum Press, New York, 1966).
S. P. Murarka, Silicides for VLSI Applications (Academic Press, New York, 1983).
A. K. Vasudevan and J.J. Petrovic, Mater. Sci Eng. A155, 1 (1992).
M. Singh and A. Bose, in Processing and Fabrication of Advanced Materials for High Temperature Applications, edited by V. A. Ravi and T. S. Srivatsan (TMS, Warrendale, PA, 1992), p. 95.
J. J. Petrovic and A. K. Vasudevan, in Intermetallic Matrix Composites II, edited by D. B. Miracle, D. L. Anton, and J. A. Graves (Mater. Res. Soc. Symp. Proc. 273, Pittsburgh, PA, 1991), p. 229.
A. Costa e Silva and M. J. Kaufman, Scripta Metall. Mater. 29, 1141 (1993).
P. S. Frankwicz and J. H. Perepezko, in High Temperature Ordered Intermetallic Alloys IV, edited by L.A. Johnson, D. P. Pope, and J. O. Stiegler (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), p. 169.
Y. Umakoshi, T. Hirano, T. Sakagami, and T. Yamane, in High Temperature Aluminides and Intermetallics, edited by S. H. Hwang, C.T. Liu, D.P. Pope, and J. O. Stiegler (TMS-AIME, Warrendale, PA, 1990), p. 111.
J.J. Petrovic and R.E. Honnell, Ceram. Eng. Sci. Proc. 11 (7-8), 734 (1990).
D. M. Shah, D. Berczick, D. L. Anton, and R. Hecht, Mater. Sci. Eng. A155, 45 (1992).
G. Petzow and G. Effenberg, Ternary Alloys—A Comprehensive Compendium of Evaluated Constitutional Data and Phase Diagrams (VCH Publishers, New York, 1993), Vol. 7.
R.W. Rice and W.J. McDonough, J. Am. Ceram. Soc. 68 (5), C-122 (1985).
A. B. Gokhale and G.J. Abbaschian, J. Phase Equilibria 12 (4), 493 (1991).
B.D. Cullity, Elements of X-ray Diffraction, 2nd ed. (Addison-Wesley Publishing Co., Reading, MA, 1978).
G.V. Samsonov and I. M. Vinitskii, Handbook of Refractory Compounds (IFI/PLENUM, New York, 1980).
T. B. Massalski, H. Okamoto, P. R. Subramania, and L. Kacprzak, Binary Alloy Phase Diagrams, 2nd ed. (ASM INTERNATIONAL, Materials Park, OH, 1990), Vol. 1.
S. C. Deevi, Mater. Sci. Eng. A149, 241 (1992).
D. A. Hardwick, P. L. Martin, and R. J. Moores, Scripta Metall. Mater. 27, 391 (1992).
Z. Y. Fu, R. Z Yuan, Z. A. Munir, and Z. L. Yang, Int. J. Self-Propagating High-Temperature Synthesis 1 (1), 119 (1992).
I. Gotman, M.J. Koczak, and E. Shtessel, Mater. Sci. Eng. A187, 189 (1994).
A. G. Merzhanov, Combustion and Flame 13, 143 (1969).
L. Brewer, R. H. Lamoreaux, R. Ferro, R. Marazza, and K. Girgis, Molybdenum: Physico-Chemical Properties of Its Compounds and Alloys, Atomic Energy Review (International Atomic Energy Agency, Vienna, 1989), Special Issues No. 7.
V. E. Ivanov, E. P. Nechiporenko, V. I. Zmii, and V. M. Kirvoruchko, in Diffusion Cladding of Metals, edited by G.V. Samsonov (Consultants Bureau, Plenum Publishing Co., New York, 1967), p. 29.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fu, M. A study of micropyretic reactions in the Mo–Si–Al ternary system. Journal of Materials Research 12, 1481–1491 (1997). https://doi.org/10.1557/JMR.1997.0204
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1997.0204