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Synthesis of Cu(II) complexes containing 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene (L) and diisobutyldithiophosphinate or isobutylxanthate. Crystal Structure of [CuL](iso-Bu2PS2)2

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Abstract

The reaction of Cu(II) complex with 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotet-radeca-4,11-diene (L) and iso-Bu2PS −2 or iso-BuOCS −2 anions gave stable paramagnetic compounds [CuL](iso-Bu2PS2)2 (I) (μeff = 1.77 μB) and [CuL](iso-BuOCS2)2 (II) (μeff = 1.76 μB). According to X-ray diffraction, the crystal structure of I is composed of discrete centrosymmetric complex cations [CuL]2+ and iso-Bu2Ps −2 anions. The CuN4 coordination unit is a square. The Cu...S distance (iso-Bu2PS −2 ) equal to 3.047 Å attests to possible S-coordination. Compounds I and II were studied by EPR.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    T. E. Kokina, R. F. Klevtsova, L. A. Glinskaya, E. G. Boguslavskii & S. V. Larionov

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  1. T. E. Kokina
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  2. R. F. Klevtsova
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  3. L. A. Glinskaya
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  4. E. G. Boguslavskii
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  5. S. V. Larionov
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Correspondence to T. E. Kokina.

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Original Russian Text © T.E. Kokina, R.F. Klevtsova, L.A. Glinskaya, E.G. Boguslavskii, S.V. Larionov, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 1, pp. 54–60.

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Kokina, T.E., Klevtsova, R.F., Glinskaya, L.A. et al. Synthesis of Cu(II) complexes containing 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene (L) and diisobutyldithiophosphinate or isobutylxanthate. Crystal Structure of [CuL](iso-Bu2PS2)2 . Russ J Coord Chem 36, 53–59 (2010). https://doi.org/10.1134/S1070328410010094

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  • DOI: https://doi.org/10.1134/S1070328410010094

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