Skip to main content
SpringerLink
Log in

Comparison of Two Preconcentration Methods for the Determination of Nickel Using a Ni–2-(2-thiazolylazo)-p-Cresol Complex: Extraction and Sorption onto Ion Exchange Resin

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

2-(2-Thiazolylazo)-p-cresol (TAC) reacts with Ni(II) at pH 6–10 and forms a 1 : 2 blue complex. The stability constant of this complex is 5.0 ± 0.3. The complex has maximum absorption at 600 nm with the molar absorptivity of 27063 L/mol cm. Two preconcentration methods for the determination of Ni (an extraction method and sorption onto an ion exchange resin) at ppm levels using a Ni−TAC complex in EtOH−H2O (1 : 1, v/v) are described. For the extraction method, the linear regression was y = 0.0375x – 0.0007, and the coefficient of determination (r2) was 0.9995. The limit of detection (LOD) was 9 µg/L, and the limit of quantification (LOQ) was 28 µg/L. The assay recovery was 83 ± 6%, and the intermediate precision (relative standard deviation (RSD), %) was 2.3%. For the method including sorption onto an ion exchange resin, the linear regression was y = 0.0391x – 0.0001, and the coefficient of determination (r2) was 0.9995. The LOD and LOQ were 7 and 25 µg/L, respectively. The assay recovery was 99 ± 6%, and the intermediate precision (RSD) was 2.2%. Sorption onto an ion exchange resin is simple and precise and offers higher recovery compared to the extraction method for Ni quantification. Based on the findings in the present study, the preconcentration method including sorption onto an ion exchange resin could be applied to the determination of Ni in wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Toxicological Profile for Nickel, Atlanta: Agency for Toxic Substances and Disease Registry, 2005.

  2. Amin, A.S. and Ibrahim, M.S., Ann. Chim., 2001, vol. 91, p. 103.

    CAS  Google Scholar 

  3. Rauf, M.A., Akhter, Z., and Kanwal, S., J. Trace Microprobe Tech., 2003, vol. 21, p. 577.

    Article  CAS  Google Scholar 

  4. Lokhande, R.S., Chaudhary, A.B., and Nirupa, S., Asian J. Chem., 2002, vol. 14, p. 153.

    CAS  Google Scholar 

  5. Rai, H.C., Kumar, A., Singh, K.B., and Kumar, R., Asian J. Chem., 2004, vol. 16, p. 299.

    CAS  Google Scholar 

  6. Ferreira S.L.C., Costa, A.C.S., and Andrade, H.A.S., Microchem. J., 1991, vol. 4, p. 63.

    Article  Google Scholar 

  7. Ferreira, S.C.L., Queiroz, A.S., Korn, M.G.A., and Costa, A.C.S., Anal. Lett., 1997, vol. 30, no. 12, p. 2251.

    Article  CAS  Google Scholar 

  8. Tan, L.V., Tu, L.N., and Chien, N.X., Eur. Chem. Bull., 2013, vol. 2, no. 6, p. 311.

    Google Scholar 

  9. Saavedra, R., Gómez, R., Soto, C., Aguayo, D., Candia, C., Yañez, J., and Zuñiga, V., Int. J. Thermophys., 2013, vol. 34, p. 1689.

    Article  CAS  Google Scholar 

  10. Sant'Ana, O.D., Jesuino, L.S., Cassella, R.J., Carvalho, M.S., and Santelli, R.E., J. Braz. Chem. Soc., 2004, vol. 15, p. 96.

    Article  CAS  Google Scholar 

  11. Cassella, R.J., Salim, V.A., Jesuíno, L.S., Santelli, R.E., Ferreira, S.L.C., and de Carvalho, M.S., Talanta, 2001, vol. 54, p. 61.

    Article  CAS  Google Scholar 

  12. Ferreira, S.L.C., Talanta, 1988, vol. 35, no. 6, p. 485.

    Article  CAS  Google Scholar 

  13. Sérgio L.C., Ferreira, L., Spinola Costa, A.C., and Andrade H.A.S., Acta Aliment., 1993, vol. 111, p. 119.

    Google Scholar 

  14. Moghadam, M.R., Shabani A.M.H., Dadfarnia, S., and Ghasemi, J., J. Iran. Chem. Res., 2012, vol. 5, no. 4, p. 255.

    Google Scholar 

  15. Songsasen, A. and Rungrojwittayakul, S., Proc. 41st National Conference, Kasetsart Univ., 2003, p. 210.

  16. Rerkpalin, W. and Songsasen, A., Abstracts of Papers, Int. Conference & Exhibition on Pure and Applied Chemistry, Bangkok, 2012, p. 29.

  17. Daryoush A., Jandaghi, E., and Taher, M. Ali, J. Braz. Chem. Soc., 2011, vol. 56, no. 1, p. 591.

    Google Scholar 

  18. Job, P., Ann. Chim. Appl., 1928, vol. 9, p. 113.

    CAS  Google Scholar 

  19. Meyer Jr., A.S. and Ayres, G.H., J. Am. Chem. Soc., 1957, vol. 79, no. 1, p. 49.

    Article  CAS  Google Scholar 

  20. International Harmonised Tripartite Guideline (ICH), (Q2B), Harmonized Tripartite Guideline, Validation of Analytical Procedures: Methodology, Proceeding of the International conference on Harmonization, Geneva, 1996.

  21. Bartram, J. and Balance, R., Water Quality Monitoring: A Practical Guide to the Design and Implementation of Freshwater Quality Studies and Monitoring Programmes, United Nations Environment Programme and the World Health Organization, 1996.

    Book  Google Scholar 

  22. Ferreira, S.C.L., Andrade, M.G.M., Lobo, I.P., and Costa, A.C.S., Anal. Lett., 1991, vol. 24, no. 9, p. 1675.

    Article  CAS  Google Scholar 

  23. Croot, P.L. and Johansson, M., Electroanalysis, 2000, vol. 12, no. 8, p. 565.

    Article  CAS  Google Scholar 

  24. Gando-Ferreira, L.M., Romao, I.S., and Quina, M.J., Chem. Eng. J., 2011, vol. 172, p. 277.

    Article  CAS  Google Scholar 

  25. Zainol, Z. and Nicol, M.J., Hydrometallurgy, 2009, vol. 99, p. 175.

    Article  CAS  Google Scholar 

  26. Moghadam, M.R., Shabani, A.M.H., Dadfarnia, S., and Ghasemi, J., J. Iranian Chem. Res., 2012, vol. 5, no. 4, p. 255.27.

  27. Berisha, V., Veliu, A., and Shala, M., J. Int. Environ. Appl. Sci., 2018, vol. 13, no. 3, p. 174.

    CAS  Google Scholar 

Download references

Funding

This research was supported by a Scientific Research no. 21.2CNHH01/ IUH 2021-2022 from Industrial University of Ho Chi Minh City, Vietnam.

Author information

Authors and Affiliations

  1. Chemical Engineering Faculty, Industrial University of Ho Chi Minh City, 70000, Ho Chi Minh City, Vietnam

    Nguyen Quoc Thang & Le Van Tan

Authors
  1. Nguyen Quoc Thang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Le Van Tan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Le Van Tan.

Ethics declarations

The authors declare that they have no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Thang, N., Tan, L. Comparison of Two Preconcentration Methods for the Determination of Nickel Using a Ni–2-(2-thiazolylazo)-p-Cresol Complex: Extraction and Sorption onto Ion Exchange Resin. J Anal Chem 77, 1413–1418 (2022). https://doi.org/10.1134/S1061934822110132

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934822110132

Keywords:

Search

Navigation