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(Met)acrylate-Containing Sterically Hindered o-Benzoquinones for free Radical Polymerization

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Abstract

New initiator monomers, derivatives of 3,5-di-tert-butyl-o-benzoquinone containing the 2‑hydroxyethyl methacrylate (HEMA) and pentaerythritol triacrylate (PETA) moieties, have been synthesized. The activity of new o-quinones has been examined in the visible light-induced polymerization (coinitiator N,N-dimethylcyclohexylamine) of oligocarbonate dimethacrylate OCM‑2. The thermal stability of the obtained polymers has been studied. Polymers have been prepared by copolymerization of the synthesized o-quinones with HEMA and PETA (initiator azobisisobutyronitrile, 80°C), and the migration of o-quinones from the products has been evaluated.

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Funding

This work was supported by the Russian Science Foundation, project no. 19-73-10173. The work was performed using the equipment of the Shared-Use Analytical Center at the Institute of Organometallic Chemistry of the Russian Academy of Sciences with the support of the grant “Providing for the development of the material and technical infrastructure of centers for shared use of scientific equipment” (project unique identifier RF–2296.61321X0017, agreement no. 075-15-2021-670).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    E. R. Zhiganshina, V. S. Lysenkov, T. I. Lopatina, M. V. Arsenyev & S. A. Chesnokov

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  1. E. R. Zhiganshina
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  2. V. S. Lysenkov
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  3. T. I. Lopatina
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  4. M. V. Arsenyev
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  5. S. A. Chesnokov
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Correspondence to E. R. Zhiganshina.

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Translated by S. Zatonsky

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Zhiganshina, E.R., Lysenkov, V.S., Lopatina, T.I. et al. (Met)acrylate-Containing Sterically Hindered o-Benzoquinones for free Radical Polymerization. High Energy Chem 56, 163–169 (2022). https://doi.org/10.1134/S0018143922030134

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