Issue 0, 1979
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Synthetic photochemistry. Part 2. Generation of benzocyclobutenols by photocyclisation of benzocycloalkenones

Marie-Christiane Carré,   Marie-Laure Viriot-Villaume  and  Paul Caubère  

Abstract

The irradiation of benzocycloalkenones (2) was examined in t-butyl alcohol and cyclisation into benzocyclobutenols (1) was observed for n= 7–9. On irradiation, substituted benzocycloalkenones (4) cyclised by an external mechanism to tricyclic benzocyclobutenols (7) and/or by an internal mechanism to alcohols (5) and/or (6), the relative ratio of these products depending on the nature of the alkyl substituent and the ring size. The results are related to the mechanism of the photoenolisation reaction.

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Article information

DOI
https://doi.org/10.1039/P19790002542
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 2542-2549

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Synthetic photochemistry. Part 2. Generation of benzocyclobutenols by photocyclisation of benzocycloalkenones

M. Carré, M. Viriot-Villaume and P. Caubère, J. Chem. Soc., Perkin Trans. 1, 1979, 2542 DOI: 10.1039/P19790002542

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